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MONITORING AND REPORTINOROGRAM ORDER NO. R5-2008-0149-04'P <br /> . 17 <br /> FORMER J.M. EQUIPMENT COMPANY 2 <br /> SAN JOAQUIN COUNTY <br /> The groundwater monitoring wells shall be sampled according to the schedule in Table 1 and <br /> the samples analyzed by the methods in Table 2, as follows: <br /> Table 1: Sampling$ Frequency (During Phase II of the H2O2 Injection Remediation) <br /> Well ID Frequency Constituent Suite(s) Monitoring Objective <br /> OW-2, OW-3, MW-4, Suite A—all wells <br /> MW-5, MW-9 Quazterly Treatment Zone° <br /> Suite B—all wells <br /> MW-6 and MW-8 &4mi--Annual (2" Suite A(2" &4 Q) <br /> Suite B 2ntl&41b Q Transition Zones <br /> MW-2 and MW-3 Semi-A hnual Suite A and Suite B <br /> 2 &4 Q Compliance3 <br /> MW-7 Annually <br /> 4+1 Q)7 Suite A and Suite B Backgrounds <br /> ' Well IN shown on attached Figure 1 <br /> 2 Constituent suite components listed in Table 2 below <br /> 3 Wells used to monitor compliance and for the presence of breakdown/byproducts of the treatment migrating beyond the expected treatment <br /> area <br /> 4 Wells used to evaluate in-situ bioremediation progress inside the treatment zone, to gauge effectiveness of H202 injection in reducing the <br /> dissolved petroleum hydrocarbon concentrations, and to monitor potential changes in groundwater geochemistry that could be attributed to <br /> the injection of oxidizing agents <br /> 5 Well used to evaluate migration of pollutants within the treatment zone.The transition well may or may not be within the zone of influence. <br /> e Well used to develop background concentrations. <br /> 7 To be sampled prior to startup(baseline) <br /> 8 All sampling conducted following a 3-well volume purge <br /> Table 2: Analytical Methods <br /> --T— <br /> Maximum Practical <br /> Constituent Method' Quantitation Limit Frequency <br /> S (Ng/L)z <br /> Suite A <br /> TPHg GC/MS 50 <br /> BTEX, MTBE, TBA, ETBE, EPA g260B 0.50 (1.0 for total As indicated in <br /> TAME, DIPE3 xylenes) Table 1 <br /> Suite B <br /> Metals, dissolved" EPA 6010B Various As indicated in <br /> Total Chromium EPA 200.7, 200.8 10 Table 1 <br /> Hexavalent Chromium I EPA 7199 2.0 <br /> Bromide EPA 300.0 100 <br /> Bromate EPA 300.1 10 <br /> Or an equivalent EPA Method that achieves the maximum Practical Quantitation Limit. <br /> ' All concentrations between the Method Detection Limit and the Practical Quantitation Limit shall be reported as an estimated value. <br /> '-BTEX=benzene,toluene, ethylbenzene, and total xylenes.MTBE=methyl tert butyl ether,TBA=tertiary butyl alcohol, ETBE=ethyl tertiary <br /> butyl ether,TAME=tertiary amyl methyl ether,and DIPE=di-isopropyl ether. <br /> Metals include barium cadmium,calcium,total chromium,copper,lead,manganese,mercury,molybdenum, and nickel. <br /> FIELD SAMPLING <br /> 2. In addition to the above sampling and analysis, groundwater elevation, electrical conductivity, <br /> DO, ORP, pH, and water temperature will be measured in the field each time a monitoring <br /> well is sampled. The sampling and analysis of field parameters is specified in Table 3. <br />