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GEOMATRIX <br /> ' Groundwater samples from MW-15 previously contained detectable concentrations of chloroform, 1,2- <br /> DCP DBCP and the organochlorine pesticide dieldrin. However, the concentrations of these <br /> constituents in groundwater have been decreasing at an exponential rate. For example, the concen- <br /> tration of 1,2-DCP decreased from 55 to 0.6 ug/C between the first sample in April 1996 and March <br /> ' 1997. There have been no concentrations of any organic constituent above the method detection limit in <br /> MW-15 since July 1997. DBCP concentrations in samples collected from MW-15 have similarly <br /> ' decreased to less than the analytical detection limit. This suggests that the elevated concentrations of <br /> 1,2-DCP and DBCP detected in groundwater samples from this well may be an artifact of well <br /> construction and may not be representative of groundwater quality in the intermediate zone. Similarly, <br /> ' the single detections of chloroform and dieldrin at concentrations slightly higher the detection limits in <br /> the first sample collected from MW-15 may also be artifacts of well construction. <br /> ' Groundwater samples collected from the four intermediate zone monitoring wells at the Facility also <br /> ' contain the inorganic constituents chloride, nitrate, and TDS at concentrations comparable to those <br /> detected in upgradient intermediate zone well MW-17. Historically, chloride concentrations range <br /> between 270 and 660 mg/C, nitrate concentration range between non-detected (less than 0.5 mg/C) and <br /> 0.42 mg/C, and total dissolved solids(TDS)concentrations range between 940 and 2,200 mg/f. <br /> Downgradient Area <br /> Analysis of groundwater samples collected from three shallow-zone monitoring wells located down- <br /> gradient of the Facility indicate that shallow groundwater has been impacted by Facility operations. <br /> ' Shallow groundwater samples collected from two of these shallow zone monitoring wells contain <br /> detectable concentrations of several organic constituents, including: <br /> • the VOCs chlorobenzene, chloroform, and 1,2-DCP; <br /> ' . the triazine pesticide atrazine; <br /> • the chlorinated herbicide dinoseb; and <br /> ' . the fumigant DBCP. <br /> In addition, groundwater samples collected from several shallow zone monitoring wells contained the <br /> t inorganic constituents ammonia, chloride, nitrate, and TDS at elevated concentrations compared to the <br /> upgradient shallow zone well (MW-16). Historically, concentrations of ammonia range from non- <br /> detected (ND) to 17 mg/f, concentrations of chloride range from 180 to 890 mg/t, concentrations of <br /> nitrate range from 34 to 400 mg/C, and concentrations of TDS range from 1,900 to 3,700 mg/C. <br /> There are no intermediate zone monitoring wells located downgradient of the Facility. However, <br /> discrete-depth groundwater samples have been collected from the intermediate zone and deeper zone at <br /> ' three locations downgradient of the Facility. These intermediate and deeper zone groundwater samples <br /> BPROMMC383%1 U8 383 37. 8 <br />