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CVATC <br /> A S S O C I A T E S I N C . <br /> presented in ATC's report titled Summary Report of Additional Subsurface Investigation, dated <br /> November 1,2002. <br /> On April 29 and 30, 2003, ATC supervised the installation monitoring well, MW9. MW-9 was <br /> installed in the northern portion of the site to a depth of 113 feet bgs to correspond with the deeper <br /> water-bearing zone encountered in boring CPTL Laboratory analytical results of a groundwater <br /> sample collected from MW-9 on May 5, 2003, indicated that hexavalent chromium and total <br /> chromium were detected at concentrations of 0.0049 and 0.0081 mg/l, respectively. Refer to ATC's <br /> report Summary Report ofAdditional Subsurface Investigation Deep Well Investigation, dated May 8, <br /> 2003 for additional information. <br /> Conceptual Remediation Design <br /> Historical analytical data indicate that there is not a feasible natural mechanism for attenuation of <br /> dissolved hexavalent chromium (Cr VI), except for dilution. The oxidizing environment in the <br /> subsurface will likely tend to maintain chromium ions in the +6 valence. Absent a reducing <br /> environment in the subsurface, monitored natural attenuation is not recommended, and an engineered <br /> solution is proposed. <br /> Based on the depth of impacted soil and the proximity to structures at the site, soil excavation and <br /> removal is not feasible. Stabilization of the chromium is recommended and should serve to inhibit its <br /> further migration. As a combined remediation effort of soil and groundwater, we propose to extract <br /> shallow groundwater, remediate the groundwater, introduce a ferrous hydroxide solution, and reinject <br /> the treated groundwater near Vaults 7 and 8 to reduce Cr VI in the subsurface to Cr III. <br /> The remediation system consists of shallow groundwater extraction and treatment, and installation of <br /> an infiltration system located near Vaults 7 and 8 (Figure 2). The purpose of this system will be to <br /> produce a dilute ferrous hydroxide solution from extracted groundwater, and infiltrate the solution as <br /> closely as possible through the migration pathways that originally contaminated the groundwater. The <br /> ferrous hydroxide solution is intended to reduce the Cr VI in the subsurface to Cr III, and stabilize Cr <br /> III as a precipitate of chromium hydroxide [Cr(OH)3]. <br /> The groundwater treatment system is expected to consist of one extraction well installed in the shallow <br /> aquifer near Vaults 7 and 8, an extraction pump, a ten gallon per minute capacity electrochemical cell <br /> with sacrificial iron anodes, a dual cartridge-type filter with pressure sensor and valves to allow <br /> switching chambers when one side becomes plugged, a PLC with sufficient inputs and outputs to <br /> control amperage of the rectifier based on flow rate, level control valves on each sump based on sump <br /> level, alarm activated pressure readings for the filter, and adjustable valve positions for the filter. The <br /> groundwater treatment system will also include interconnecting piping, fittings and valves, level <br /> sensors and level control valves for each sump, a flow transmitter, a pressure sensor for the filter, a <br /> three-way control valve to switch the filters, a power supply panel, electrical distribution wiring from <br /> the plant,and perforated or removable vault bottoms. <br /> Currently, monitoring well MW-5 is used as a sentinel well with respect to WP-1. Should elevated <br /> concentrations of chromium be detected in groundwater samples collected from MW-5, a second <br /> component is proposed as a contingency measure consisting of a hydraulic barrier that would be <br /> intended to prevent further migration of contaminants in the downgradient direction toward Stockton <br /> W:\62583Vetten\Concept Design Outine.doc 3 <br />