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Pilot Study Workplan November 7, 2014 <br /> Project#54.62563.0001 Page 6 <br /> 4.0 NATURE AND EXTENT OF CONTAMINATION <br /> 4.1 CONTAMINANTS IN SOIL <br /> In December 1988, Weiss Associates conducted the initial soil investigations in the vicinity of the previously <br /> referenced vaults to determine whether the vault contents had impacted the soil beneath the vaults. <br /> The samples collected beneath Vaults 1, 5, and 6 were analyzed for ethylene glycol and propylene glycol. <br /> Initial laboratory results reported ethylene and propylene glycol as detected beneath Vaults 1 and 6. The <br /> samples collected beneath Vaults 7 and 8 were analyzed for soluble total chromium, soluble copper, total <br /> sodium, and total sulfate. Additionally the Vault 8 samples were analyzed for soluble hexavalent chromium, <br /> total calcium, and total chloride. All analytes were present at or above method detection limits beneath <br /> Vaults 7 and 8. Based on analytical data from soil samples collected beneath the vaults it appears that <br /> releases primarily occurred from Vaults 1, 6, 7, and 8. <br /> In January 1991, PC Exploration drilled three angle borings (61-A, B6-A, and 138-A) and three vertical borings <br /> (61-13, 66-13, and 68-13) in the vicinity of Vaults 1, 6, and 8 under the direct supervision of a Weiss Associates <br /> geologist. These borings were drilled in an attempt to define the extent of soil contamination and to <br /> determine if groundwater impact had occurred. Borings B1-A, B6-A, and 68-A were drilled to depths of 45.3, <br /> 37.6 and 40.8 feet, respectively. Borings B1-13, 136-13, and 68-13 were drilled to depths of 91, 86, and 96 feet, <br /> respectively. <br /> In samples collected near Vault 1, glycols were detected in several soil samples collected from angle boring <br /> B1-A, but were not detected in the soil samples collected between 50.3 and 65.7 feet below grade in the <br /> vertical boring samples (61-13). In Vault 6 glycols were not detected in the soil samples collected deeper than <br /> 33.4 feet in the angle boring (66-A) and were not present in the vertical boring samples (66-13). The soluble <br /> total chromium, total chromium, and total hexavalent chromium analytical results for the Vault 8 samples <br /> were below their respective DHS, STLC and TTLC limits. Although total sodium analytical results did not <br /> significantly exceed the sodium background concentrations, the total calcium and total chloride results did <br /> exceed their respective background concentrations. <br /> In November 2001 and January 2002, ATC advanced borings SB1 through SB9. The borings were placed in <br /> locations upgradient and downgradient from the closed vaults to evaluate the lateral extent of impacted soil. <br /> Hexavalent chromium was detected at relatively low concentrations in soil samples from borehole locations <br /> SB1 through SB9 from the 20 and 40-foot depths with the exception of SB8 at 40 feet. <br /> The highest concentrations of hexavalent chromium were detected in the samples from off-site boring SB9 at <br /> 1.5 and 2.6 milligrams per kilogram (mg/kg). Concentrations of hexavalent chromium in the samples from <br /> borings SB1, SB2 and SB3 ranged from 0.09 mg/kg to 0.61 mg/kg. Concentrations of hexavalent chromium <br /> were lowest in borings SB4 through SB8, ranging from 0.0010 mg/kg to 0.0074 mg/kg. Hexavalent chromium <br /> was not detected in the soil sample from SB8 at 40 feet bgs above method detection limits. The Total <br /> Threshold Limit Concentration (TTLC) for hexavalent chromium compounds is 500mg/kg. <br /> Hexavalent chromium was not detected in any soil samples collected from borehole locations MW4 through <br /> MW8 from the 40 and 50-foot depths. <br /> The three samples collected from SB10 were analyzed for alkalinity by EPA Method 310.1, ammonia by <br /> Standard Method 4500, nitrate by EPA Method 300, total organic carbon (TOC) by ASTM D2974, Hexavalent <br />