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Geologfeal recklucs/Ac. Page 9 <br /> ' IRAP—Pilot Test <br /> Project No. 425.2 <br /> March 21,2005 <br /> ' 4.8 Soil Sampling <br /> ' Discrete soil samples will be collected in 6.0-inch brass liners using a 2.0-inch modified <br /> California split spoon sampler. All soil samples will be sealed with Teflon, capped with <br /> plastic end caps, labeled and placed in a cooler at 4° Celsius for transport to the laboratory <br /> ' following Chain of Custody protocol. <br /> Chemical Testing <br /> ' The soil samples will be analyzed for chemical appropriate constituents. <br /> 4.9 Sparge Point <br /> tThere are several commercially available sparge points to consider for use at the site. The <br /> apparatus selected will be chosen after consultation with the ozone equipment subcontractors. <br /> ' 4.10 Ozone Sparging Equipment <br /> ' The ozone sparging equipment will consist of an ozone generator, air compressor, manifold <br /> piping, pressure gauges and distribution valves. Three bids must be solicited for the project <br /> in order to stay in compliance with USTCFP requirements. <br /> The required injection pressures and flow rates utilized in the sparging system must be <br /> sufficient to overcome the head pressure of the overlying water column and the capillary <br /> ' pressure of the subsurface soil. The flow rates must be as high as possible to deliver ozone to <br /> the maximum possible area of the plume. The injection pressures will be lower than the <br /> pressures which may cause the lateral spreading of contamination plume. - k, <br /> Initially, air will be injected into the subsurface to open up the soil pore space. The <br /> pressurized air will be delivered through diffusers that will introduce fine bubbles into the <br /> ' soil. The bubbles will form micro-channels or preferential pathways through which the air <br /> will flow. While in the channels the air will allow the gasoline to undergo a phase transfer <br /> from dissolved to vapor phase. After the initial air injection, the ozone will then be <br /> ' introduced into the soil at a concentration of approximately 5% ozone & 95% oxygen. The <br /> system will operate in pulse mode to allow the micro-channels to repeatedly fill and empty <br /> which will cause a reaction chamber type response. The ozone will oxidize the MTBE as <br /> ' well as other constituents and unconsumed oxygen will serve to augment the bio-remediation <br /> capacity of the aquifer. <br /> ' The EPA has stated that 1 PSI of injection pressure is necessary for every 2.3 feet of <br /> hydraulic head. (USEPA: How to Evaluate Alternative Cleanup Technologies for <br /> ' Underground Storage Tank Sites, May, 1995). Water Table is at about 12 feet bgs. This <br /> would require an injection pressure of 4.4 PSI(10 feet divided by 2.3). <br /> 1 <br />