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4 <br /> ' COPC concentrations that make this risk assessment conservative in nature These conditions will result in <br /> a significant overestimation of risk and excessively low RBSLs <br /> ' 3.3.2 ASTM RBCA Fate and Transport Algorithms: The ASTM guidelines and the GSI RBCA <br /> Spreadsheet System used in this analysis employ a series of simplified fate and transport models for <br /> predicting COPC concentrations at points of exposure The simplified analytic nature of these models, <br /> ' particularly those used to simulate volatilization and transport of vapor emissions to ambient and indoor <br /> air, often result in grossly over-estimated COPC exposure point concentrations (Sanders and Stern, 1994, <br /> GSI, 1995 and 1997, AEHS, 1997, Javaherian, 1994 and 1997), in turn,these result in over-estimation of <br /> health risks and lower RBSLs In fact, GSI (1995 and 1997)warns against delineation of cleanup levels <br /> based on the use of its formulation for vapor intrusion to indoor air Examples of physical and chemical <br /> processes ignored by the simplified ASTM vapor transport models include <br /> • loss mechanisms -absence of loss mechanisms such as biodegradation and adsorption result in over- <br /> estimation of vapor and contaminant flux to ambient and indoor air, <br /> • depleting contaminant source-use of a non-depleting, constant source results in an unlimited supply of <br /> contaminated vapor and an over-estimation of vapor and contaminant flux to ambient and indoor air <br /> over time, and <br /> • water movement-absence of water movement through subsurface soils results in an over-estimation of <br /> I ' air-filled porosity and vapor and contaminant flux to ambient and indoor air <br /> 3.3.3 Representation of Site Conditions: In the absence of site-specific data, the ASTM RBCA <br /> process promotes the use of conservative default values for various parameters representing site conditions <br /> This RBCA analysis consistently incorporated conservative assumptions for selection of input parameters, <br /> while attempting to maintain a reasonable, site-specific evaluation Examples of conservative assumptions <br /> ' used to formulate input parameters include <br /> The maximum chemical concentrations in groundwater over the past two years are representative of <br /> ' current and future source concentrations, <br /> The entire soil column is impacted at levels detected in confirmation soil samples, <br /> The onsite building exist directly over the locations of maximum groundwater concentrations detected <br /> ' over the past two years, <br /> Cracks exist in the foundation of the onsite building, and <br /> The paved surface has a negligible impact on vapor emission to outdoor air <br /> Use of these conservative assumptions result in an over-estimation of health risks and lower RBSLs <br /> 3 3.4 Standard Exposure Factors Standard exposure scenarios evaluated in this RBCA analysis <br /> incorporate the most likely site-specific exposure pathways and represent the greatest potential for <br /> exposure to contaminants at the site Conservative assumptions consistent with state and federal <br /> ' guidelines were used to conceptualize the exposure scenarios These methods and procedures contribute to <br /> an overall overestimation of potential exposure <br /> Numerous conservative exposure assumptions serve as the basis for exposure parameters adopted by <br /> ASTM(1995) Duration, frequency, and other input parameters were selected to represent the maximally <br /> exposed individual and are not an accurate portrayal of time spent at a place of business or residence The <br /> quantitative effect of these uncertainties would be considered significant in overestimating overall potential <br /> health risk <br /> ' 13 <br />