ARCHIVED REPORTS XR0006486 - Laserfiche WebLink

Home Browse Search

REG 603 UPDATE-7 3/24/92 • the vacuum pump. After the vapor stream leaves the vacuum pump, it is pushed into the thermal oxidizer (RXL 400 ) which oxidizes the gasoline range hydrocarbon vapors at no less than 1400°F and no greater than 1550 F. Influent samples are obtained from the exit of the pump and effluent samples are obtained from the stack of the thermal oxidizer. The gasoline range hydrocarbons are oxidized into heat, CO2 and water vapor, see Figure 7 and UPDATE STATUS REPORT #5 . A portable ambient air PID-GC (Photovac 1OS50 packed column) is used at the site to sample the influent and effluent of the REMOX oxidizer, and the individual wells (MW1, MW2-3, MW10 and EX-41' ) , see Tables 2, 3 and 4 . On October 22, and 24, 1991, "Tedlar" bag samples were obtained of the influent and effluent of the REMOX incenerator and on January 20, 1992, a influent sample was obtained. These samples were analyzed for TFH and BTEX along with screening for Tetrachloroethylene (PCE) , Trichloroethylene (TCE) and 1, 2, -Dichloroethane (DCE)using a Shi.madzu GC-FID chromatograph mounted permanently in WEGE ' s portable laboratory. These compounds have the following retention times in the above chromatograph, DCE = 2. 079 minutes, TCE = 3 . 023 minutes and PCE = 3 . 75 minutes. Prior to sampling the wells or the system, a calibrant prepared from fresh gasoline is injected into the GC- PID. The resulting chromatogram has numerous responses. The microprocessor of the GC-PTD computes the area, per response, in volt seconds, and assigns a peak #, and retention time. The sum of all the responses are then used to obtain a mg/L per volt second calibrant factor, which is used to calculate mg/L as gasoline vapor from each analysis produced. Using these mg/L values produced from the anlaysis of the different vapor recovery wells and the influent to the oxidizer, and the pressure differential created at the orifice to determine flow rates for each well and the influent to the oxidizer; pounds per day can be computed. The pounds per day values for each well and the influent are then averaged to the preceeding site visits pound per day and then multiplied by the number of days the system operated between visits to estimate the total pounds each well and the system has removed for that time period. This poundage is then added to the accumulated poundage of the previous visit to update The effluent ..,rvl .-. is o ,-e%y1T111�Orl the total pounds removed mo aaue. the e� fluent saxAmple is �-...L,.... ._ in the same fashion, but also includes natural gas flow along with the influent orifice flow rate. C. 2 . SAMPLING VAPOR STREAMS The vapor samples are obtained by attaching a dedicated air tight 60 cc syringe to a sample port on the vapor recovery manifold, well side of the orifice plate, with air tight fitted polytubing. The sample port is then opened and the syringe is purged by PAGE 8