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*ftliv Now MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 2 APPLICATORS AND ALL OTHER HANDLERS: Please refer to the product label for personal 15. REGULATORY INFORMATION: protective clothing and equipment. NOTICE:The Information herein is presented in good 9. PHYSICAL AND CHEMICAL PROPERTIES: faith and believed to he accurate as of the effective date shown above. However,no warranty,express or BOILING POINT:290'F(143'C)(solvent) implied, is given. Regulatory requirements are subject VAPOR PRESSURE: <10 mmHg @ 25'C to change and may differ from one location to another; VAPOR DENSITY:Not determined it is the buyer's responsibility to ensure that its activi- SOLUBILITY IN WATER: Emulsifiable ties comply with federal, state or provincial,and local SPECIFIC GRAVITY:1.079 laws. The following speck information is made for APPEARANCE: Red liquid the purpose of complying with numerous federal,state ODOR:Solvent-type odor or provincial,and local laws and regulations. U.S.REGULATIONS 10. STABILITY AND REACTIVITY: SARA 313 INFORMATION:This product contains the STABILITY:(CONDITIONS TO AVOID)Avoid heating following substances subject to the reporting require- above 50'C(122'F).Chlorpyrifos undergoes exother- ments of Section 313 of Title III of the Superfund mic decomposition at approximately 130'C (266'F) Amendments and Reauthorization Act of 1986 and 40 which can lead to higher temperatures and violent de- CFR Part 372: composition if generated heat is not removed. Con- tains petroleum derivative Solvent-will burn. CHEMICAL NAME CAS NUMBER CONCENTRATION INCOMPATIBILITY: (SPECIFIC MATERIALS TO xyene 001330-e0-7 azo% AVOID)None known. SARA HAZARD CATEGORY:This product has been HAZARDOUS DECOMPOSITION PRODUCTS: Un- reviewed according to the EPA "Hazard Categories" der fire conditions, hydrogen chloride, ethyl sulfide, promulgated under Sections 311 and 312 of the Su- diethyl sulfide and nitrogen oxides can be formed. perfund Amendment and Reauthorization Act of 1986 HAZARDOUS POLYMERIZATION:Not known to oc- (SARA Title III) and is considered, under applicable cur. definitions, to meet the following categories: 11. TOXICOLOGICAL INFORMATION: An immediate health hazard A delayed health hazard MUTAGENICITY (EFFECTS ON GENETIC MATE- A fire hazard RIAll Results of in-vitro("test tube")and animal mu- TOXIC SUBSTANCES CONTROL ACT(TSCA): All tagenicity,tests on the aromatic solvent have been neg- ingredients are on the TSCA inventory or are not re- ative. Based on a majority of negative data and some quired to be listed on the TSCA inventory. -� equivocal or marginally positive results,chlorpyrifos is STATE RIGHT-TO-KNOW: The following product considered to have minimal mutagenic potential. components are cited on certain state lists as men- tioned. Non-listed components may be shown in the 12. ECOLOGICAL INFORMATION: composition section of the MSDS. ENVIROMENTAL FATE: MOVEMENT&PARTITIONING:Based on information CHEMICAL NAME CAS NUMBER LIST for chlorpyrifos and components of Aromatic 100. Bioconcentration potential is moderate (BCF is be- xylene 001330-20-7 NJ1 NJ2 NJ3 tween 100 and 3000 or Log Pow between 3 and 5). PA1 PA3 DEGRADATION & PERSISTENCE: Based on infor- Chlorpyrifos 002921-88-2 NJ3 PA1 PA3 mation for chlorpyrifos. NJ1=New Jersey Special Health Hazard Substance The photolysis half-life in water is 3-4 weeks. tpresent at greater than or equal to 0.1%). Tropospheric half-life is estimated to be 1.4 hours. JJ2=New Jersey Environmental Hazardous Sub- Degradation is expected in the soil environment within stance(present at greater than or equal to I-0%). days to weeks. NJ3=New Jersey Workplace Hazardouos Substance Ur aerobic soil conditions the halt-life is generally (present al greater than or equal to 1.0° ) Under adays. PAI=Pennsylvania Hazardous Substance(present at greater than Based on information for components of Aromatic 100. Biodegradation under aerobic static laboratory condi- PA3=Pennsylv equalania Environmental Hazardous Sub- to 1.0%). stance(present at greater than or equal to N 0%)- tions is high(BOD 20 or BOD28/ThOD is>40%). OSHA HAZARD COMMUNICATION STAN ECOTOXICOLOGY: Based on information for chlor- STANDARD* This product is a"Hazardous Chemical" as defined pyrifos. by the OSHA Hazard Communication Standard, 29 Material is very highly toxic to aquatic organisms on an CFR 1910.1200. acute basis (LC50/EC50 <0.1 mg/L in most sensitive NATIONAL FIRE PROTECTION ASSOCIATION species). (NFPA)RATINGS: Material is highly toxic to birds on a dietary basis(LC50 between 50 and 500 ppm). Material is moderately toxic to birds on an acute basis Category Raring (LD50 is between 51 and 500 mg/kg). Health 2 Based on information for Aromatic 100. Flammability 2 Material is moderately toxic to aquatic organisms on Reactivity 1 an acute basis(LC50/EC50 is between 1 and 10 mg/L COMPREHENSIVE ENVIRONMENTAL RESPONSE in most sensitive species). COMPENSATION AND LIABILITY ACT (CERCLA, Material is practically non-toxic to birds on a dietary or SUPERFUND):This product contains the following basis(LC50 is>5000 ppm). substance(s)listed as"Hazardous Substances"under Material is practically non-toxic to birds on an acute CERCLA which may require reporting of releases: basis(LDsO is>2000 mg/kg). 13. DISPOSAL CONSIDERATIONS: chemical Name CAS Number RQ %in Product DISPOSAL METHOD:Do not contaminate food,feed, Chlorpyrifos 002921-88-2 1 449% or water by storage or disposal. Pesticide wastes are 16. OTHER INFORMATION: toxic. Improper disposal of excess pesticide. spray MSDS STATUS: mixture,or rinsate is a violation of federal law. If these Revised Sections: 3&8 wastes cannot be disposed of according to label in- Reference: DR-0352-3817 structions,contact your State Pesticide or Environmen- Replaces MSDS dated: 12/6/99 tal Control Agency,or the hazardous waste represen- Document Code: D03-062-003 tative at the nearest EPA regional office for guidance. Replaces Document Code: D03-062-002 14. TRANSPORT INFORMATION: The Information Herein Is Given In Good Faith,But No Warranty,Express Or Implied, Is Made. Consult Dow For DOT regulatory Information, if required, consult AgroSciences For Further Information. transportation regulations,product shipping papers,or Trademark of Dow AgroSciences contact your Dow AgroSciences representative. Database and format copyright Q by C&P Press. All rights reserved. Powered by C&P Press.