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' 3.0 GROUNDWATER MONITORING <br /> • 3.1 Groundwater Sampling Activities <br />' JJW Geosciences, Inc. (JJW) conducted groundwater monitoring and sampling activities on <br /> May 29, 2002. Prior to purging the wells and collecting groundwater samples, we measured <br />' and recorded the depth to static groundwater in the five wells. We present current <br /> groundwater gradient and flow directions in Table I. Following water depth measurements, we <br /> used a 12-volt DC pump to purge the groundwater monitoring wells until at least two or more <br />' of the readings for temperature, pH, conductivity, and oxidation-reduction potential (ORP) <br /> approximately stabilized or three well volumes were purged. Following well purging and <br /> recharge, we collected groundwater samples with polyethylene, well-dedicated disposal <br />' bailers and poured the collected groundwater into precleaned 40 milliliter glass vials and 250 <br /> milliliter amber glass jars. JJW experienced no ambient petroleum-like odors above the <br /> monitoring wells. Following collection, we immediately placed the water samples on ice in a <br />' cooler. Specific site conditions and sampling parameters can be found in the Well Sample <br /> Field Logs included in Appendix A. <br />' JJW transported the groundwater samples under chain-of-custody to Kiff Analytical <br /> (Certification No. 2236), a State of California certified analytical laboratory. The groundwater <br /> samples were analyzed for the following parameters. <br />' Total petroleum hydrocarbons as gasoline, TPH-g (EPA method 82606). <br /> The aromatic fuel components benzene, toluene, ethylbenzene, and xylenes (BTEX) <br />' (EPA method 8260B). <br /> Fuel oxygenates MTBE, DIPE, ETBE, TAME, tert-butanol, methanol, ethanol <br /> (EPA method 82606). <br />' 1,2 dichloroethane (1,2 DCA) and 1,2 dibromoethane (1,2 DBA) (EPA method 8260B). <br />' Cumulative groundwater analytical results are summarized in Table ll. The analytical <br /> laboratory data sheets can be found in Appendix B. <br /> 3.2 Groundwater Sample Laboratory Analytical Results <br />' Laboratory analyses indicated that the aromatic volatile hydrocarbons (BTEX) and total <br /> petroleum hydrocarbons as gasoline (TPH-g) were not detected above the method reporting <br />' limits in any of the five Monitor wells. Additionally, none of the seven oxygenates nor the lead <br /> scavengers 1,2 DCA and 1,2 DBA were detected above the method reporting limit in any of <br /> the five wells. <br />' See Table II for Cumulative Groundwater Analytical Results. The analytical laboratory data <br /> sheets can be found in Appendix B. <br /> 3.3 Groundwater Flow ©irection and Gradient <br />' The shallow groundwater was calculated to flow toward the north (N 9 E) with a groundwater <br /> gradient of approximately 0.0046 tuft. This is consistent with data collected from previous <br /> sampling events. <br />' 4 JJW GEOSCIENCES Inc. <br />