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California Freight Safety Manual and IIPP The provisions set forth by the Federal Hazard Communication Program dictate that all containers of hazardous materials must be properly labeled. All containers of hazardous materials used must have, at a minimum, the original label provided by the manufacturer or a locally prepared label describing its contents and hazards involved. 1. Solvents a. Halogenated Solvents Characteristics: These products are usually clear, rapidly evaporating solvents containing chlorinates. They generally exhibit low flammability and have the consistency of water. They have a mild odor and are used in painting, stripping and other operations. Examples of chlorinated solvents are 1,1,1-Trichloroethane, perch loroethylene, methylene chloride, and Freon products. Health Hazards: Most solvents are irritating to the eyes and upper respiratory tract. Excessive, repeated exposure to the skin may produce dermatitis and drying of the skin due to the de-fating properties of the solvents. Most are toxic and may be harmful or fatal if swallowed. Inhalation of excessive vapors may produce narcotic effects by depressing the central nervous system. Typical symptoms of overexposure include dizziness, nausea, and light-headedness in some individuals. Excessive repeated exposure to some solvents may produce chronic health effects on organs such as lungs, liver, kidney, and nervous system. Some solvents have been shown to produce cancer in laboratory animals. Compressed Freon products may produce "freeze burns" on the skin and eyes when released. Very high concentrations of vapors may be dangerous to life and health. Personal Protective Equipment/Handling: Solvents should be handled with respect. Avoid any unnecessary exposure. Never wash hands in solvents. Wash with soap and water after using solvents. Avoid excessive skin contact. Use chemically resistant gloves if necessary. Avoid inhalation of vapors when possible. Use air-supplying respirators in areas of high concentration. Avoid contact with eyes. Use chemical goggles for protection. Provide ventilation when possible. Avoid contact with strong oxidizers (acids) and reactive metals (magnesium, aluminum powders). Emergency/Special: In the event of eye contact, flush eyes for 15 minutes with water. Wash skin with soap and water. Remove soaked clothing and wash before reuse. Do not allow wet clothing to remain in prolonged contact with skin. If ingested, do not induce vomiting, and seek medical attention immediately. Excessive inhalation should be treated by removing to fresh air. Apply artificial respiration if necessary. In the event of a major spill, evacuate the area and call the fire department. Avoid drainage into water sewage system. Revised January 1,2019 Page 76