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Mr. Shelby Lathrop - 2 - 3 April 2008 <br /> Former Tosco Bulk Terminal No. J13 <br /> detected in source area well MW-2 at 480 pg/L. TBA was also detected at 140 pg/L in <br /> downgradient wells MW-16 and MW-17B. <br /> The Report also describes the results of groundwater monitoring following the first in a series <br /> of planned bi-weekly source area oxygen injections. The initial series of bottled oxygen <br /> injections was implemented over four days on 17, 19, 20, and 21 December 2007 at a rate of <br /> about 13 pounds (lbs) per well per day. Oxygen was injected into nine A-zone (IP-1 to IP-9) <br /> and three B-zone (IP-10 to IP-12) injection points. The objective is to maintain dissolved <br /> oxygen (DO) levels at 10 milligrams per liter (mg/L) or greater to enhance the biodegradation <br /> of residual COCs. <br /> DO concentrations were measured in the field in monitoring wells MW-2, MW-8, MW-14, MW- <br /> 16, MW-1713, MW-19C, MW-20, and piezometers P-1 through P-6. Pre-injection DO <br /> concentrations ranged from 0.15 mg/L in MW-2 to 5.45 mg/L in P-5. Upon observing the well <br /> construction prior to the injections, SECOR believed the existing well construction was <br /> unsuitable for air injection, since oxygen injected into A-zone wells would most likely migrate <br /> upwards to the ground surface through the filter pack and thus prevent attainment of the target <br /> DO concentration of 10 mg/L. To address this problem, SECOR installed diffuser tips near the <br /> bottom of each shallow injection well. At the end of the four-day series of injections, DO <br /> concentrations ranged from 0.30 mg/L in P-2 to 5.1 mg/L in MW-17B, indicating that the <br /> diffuser tips did not significantly improve the capacity of the wells to increase DO <br /> concentrations in groundwater. Based on the results of the initial four-day injections, SECOR <br /> is considering installing additional DO injection points in the vicinity of source area wells MW-2 <br /> and MW-8 and upgradient of the well clusters MW-16/MW-17B/MW-18C and MW-20/MW- <br /> 21 B/MW-22C. <br /> ConocoPhillips proposes to review pilot test monitoring results with Regional Water Board staff <br /> after the initial 60-day test of oxygen injection capacity to assess whether the application <br /> frequency and/or application rate should be adjusted to more or less than the anticipated 13 Ib <br /> per day rate for the remainder of the 60-day test. Based on discussions with Regional Water <br /> Board staff, ConocoPhillips will determine whether an additional 60-120 days of application <br /> and/or additional well installations are appropriate. If concentrations of constituents are <br /> observed in excess of baseline concentrations, ConocoPhillips proposes to reduce or cease <br /> oxygen injections based on discussions with Regional Water Board staff. <br /> ConocoPhillips conducts groundwater monitoring at the Site pursuant to Monitoring and <br /> Reporting Program (MRP) No. R5-2004-0824. The hydrostratigraphy underlying the Site is <br /> described as consisting of three progressively deeper layers called the A, B, and C zones. The <br /> A-zone occurs at depths of about 10 to 25 bgs, the B-zone from 30 to 50 feet bgs, and the C- <br /> zone from 55 to 75 feet bgs. ConocoPhillips conducted groundwater monitoring for the fourth <br /> quarter on 30 November 2007. In the 31 January 2008 Fourth Quarter and Annual 2007 <br /> Groundwater Monitoring Report (Annual Report), the groundwater gradient and flow direction <br /> in the three zones were calculated to range from 0.03 feet per foot (ft/ft) to the southeast to <br /> 0.004 ft/ft towards the west. <br /> During the fourth quarter, the highest concentration of TPHd was 160 pg/L in MW-4. MTBE, <br /> toluene and xylene were detected below WQOs. TBA was detected at 72 pg/L in the B-zone <br /> well MW-21 B. Concentrations of TPHg, MTBE and TBA, which were once detected at <br />