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Mr. Shelby Lathrop - 2 - 16 November 2007 <br /> Former Tosco Bulk Terminal No. 100 ._ <br /> (TPHg), di-isopropryl ether (DIPE), ethyl tertiary butyl ether (ETRE), and tertiary amyl methyl <br /> ether (TAME). However, concentrations of these constituents are significantly diminished. <br /> Most recently, TBA, TPHd, and MTBE have had the highest concentrations. During 2007, A- <br /> zone well MW-2 contained the maximum TBA concentration of 670 micrograms per liter <br /> (pg/L). TBA was also detected in the B-zone at 82 pg/L in MW-21 B and in the C-zone at <br /> concentration of 46 pg/L in MW-22C. Downgradient well MW-20 had the maximum MTBE <br /> concentration at 15 pg/L, and downgradient well MW-18C had the maximum TPHd <br /> concentration at 97 pg/L. Concentrations of TPHg, TPHd, MTBE and TBA, which were once <br /> detected at thousands of pg/L in source area wells MW-14 and MW-8, were largely non-detect <br /> in these wells in 2007, with the exception of TPHd and MTBE which were detected below their <br /> respective water quality objectives (WQOs). <br /> The proposed Pilot Study will consist of injecting oxygen into nine A-zone (IP-1 to IP-9) and <br /> three B-zone (IP-10 to IP-12) injection points to enhance the biodegradation of residual CDCs. <br /> Oxygen injection is proposed for a 60-day period using bottled oxygen at a rate of about 13 <br /> pounds (lbs) per well per day. The objective will be to maintain dissolved oxygen levels at 10 <br /> milligrams per liter (mg/L) or greater. <br /> Groundwater monitoring to characterize baseline, source area, downgradient and C zone <br /> conditions is proposed from eight groundwater monitoring wells (MW-2, MW-8, MW-10, MW- <br /> 14, MW-16, MW-17B, MW-19C, and MW-20). The baseline monitoring analyte list will consist <br /> of field parameters including dissolved oxygen (DO) and ferrous iron, select metals including <br /> chromium, TPHg TPHd, oxygenates, select nutrients, methane, biochemical oxygen demand <br /> (BOD), chemical oxygen demand (COD), and heterotrophic aerobic bacteria plate count. <br /> Following initiation of the test, groundwater monitoring for this list of analytes will be conducted <br /> from these eight monitoring wells at 60 days, three months, and six months. <br /> Prior to and immediately subsequent to oxygen applications, for the first five days, DO <br /> concentrations will be measured in the field in monitoring wells MW-2, MW-8, MW-14, MW-16, <br /> MW-17, MW-19C, MW-20, and piezometers P1 through P6. ConocoPhillips proposes to <br /> review pilot test monitoring results with Regional Water Board staff after the initial 60-day test <br /> of oxygen injection capacity to assess whether the application frequency and/or oxygen <br /> application rate should be adjusted to more or less than the anticipated 13 Ib per day rate for <br /> the remainder of the 60-day test. Based on discussions with Regional Water Board staff, <br /> ConocoPhillips will determine whether an additional 60-120 days of application are <br /> appropriate. If concentrations of analyzed constituents are observed in excess of baseline <br /> concentrations, ConocoPhillips proposes to reduce or cease oxygen injections based on <br /> discussions with Regional Water Board staff. <br /> ConocoPhillips will submit a remedial implementation start-up report within four weeks of <br /> initiating oxygen injections and summary reports and after collection of the three-month and <br /> six-month samples. If little or no change to groundwater quality is evident, ConocoPhillips will <br /> propose in their summary report to continue to implement the oxygen injection events. <br /> Our comments are provided below. <br /> 1. Regional Water Board staff concur with implementation of the Pilot Study as proposed by <br /> ConocoPhillips. Please provide 48 hours notification prior initiation of the test and submit a <br />