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Mr. Mike Pitta - 2 - 19 December 2006 <br /> Hydrocarbons (TPH) as gasoline was reported at a maximum concentration of 130 milligrams <br /> per liter (mg/L), TPH diesel at 5.4 mg/L, benzene at 9,900 micrograms per liter (ug/L), and <br /> methyl tertiary butyl ether (MTBE) at 200,000 ug/L. Groundwater samples were collected for <br /> natural attenuation parameters in the fourth quarter 2005. Sulfate, ferrous iron, and methane <br /> were detected in source area wells at higher concentrations than the plume perimeter wells <br /> suggesting that anaerobic biodegradation of the petroleum hydrocarbons is occurring. <br /> The Soil Remediation Report describes the discharge of transmix fuel (gasoline and diesel <br /> mixture) on 24 July 2006 and associated remedial response activities. The release occurred <br /> from a pump back-pressure valve in the manifold area of the site. The volume discharged is <br /> unknown; however, approximately 160 gallons of SPH were recovered from the containment <br /> pad, surface water catch basin, and hand-excavated trenches and sumps. Approximately 450 <br /> gallons of petroleum-impacted groundwater were recovered from the remedial excavation <br /> area. Visibly stained soils were removed by hand-excavation down to the groundwater table <br /> about 3 feet deep across an area measuring 23 feet wide by 70 feet long. Approximately 189 <br /> tons of soil and surface gravel were excavated and placed in covered roll-off bins. The lateral <br /> extent of excavation was limited by existing infrastructure though stained soils related to the <br /> transmix discharge were reportedly completely removed from the vadose zone. <br /> Seventeen sidewall soil confirmation samples and two groundwater characterization samples <br /> were collected from the remedial excavation area. The samples were analyzed for benzene, <br /> toluene, ethylbenzene, and xylenes (BTEX compounds), and five fuel oxygenates of MTBE, <br /> ethyl tertiary butyl ether (ETBE), diisopropyl ether (DIPE), tertiary amyl methyl ether (TAME), <br /> and tertiary butyl alcohol (TBA) using EPA Method 8260B, and TPH gasoline, TPH jet fuel, <br /> and TPH diesel using EPA Method 8015M. Maximum soil sample chemical concentrations <br /> were 29,000 milligrams per kilogram (mg/kg) TPH diesel; 9,600 mg/kg TPH gasoline; 4,000 <br /> mg/kg benzene; and 9,000 micrograms per kilogram (ug/kg) MTBE. Maximum groundwater <br /> sample chemical concentrations were 31 mg/L TPH diesel; 39 mg/L TPH gasoline; 4,800 ug/L <br /> benzene; 850 ug/L MTBE. Groundwater sample chemical concentrations were within the <br /> range of historical data from nearby monitoring well SP/M-9. Regional Water Board staff in a <br /> teleconference on 12 October 2006 concurred with KMEP's request to backfill the excavation <br /> based on complete removal of soils containing SPH. <br /> The Feasibility Study (FS) was proposed in the Soil Remediation Report to re-evaluate <br /> monitored natural attenuation (MNA) as the preferred remedial alternative to address <br /> groundwater pollution at the site. Based on the range of current manifold area soil and <br /> groundwater petroleum hydrocarbon concentrations compared with historical site data, KMEP <br /> recommended that MNA should remain as the selected remedial alternative with <br /> contingencies for SPH removal if present in the future. <br /> REGIONAL WATER BOARD REVIEW COMMENTS <br /> Figures were provided in the Annual Report tabulating groundwater chemical data for the two <br /> semiannual sampling events. Although a similar depiction was referenced in the First <br /> Semiannual Report as Figure 4, the version of Figure 4 provided in the document showed <br /> shallow groundwater elevation data for May 2005. Note that in accordance with Monitoring <br /> and Reporting Program (MRP) No. R5-2005-0815, groundwater monitoring reports should <br /> include isoconcentration contour maps for chemical constituents. These maps should be <br />