Laserfiche WebLink
Mr. Joe Aldridge -2 - 22 April 2009 <br /> NuStar Terminals Stockton Facility <br /> of dissolved phase petroleum hydrocarbons were observed in ST/MW-1 and PS/P-12. <br /> Maximum concentrations in these two wells included TPHg and TPHd at 160,000 micrograms <br /> per liter (pg/L) and 220,000 pg/L, respectively, and benzene at 16,000 pg/L, toluene at <br /> 8,100 pg/L, ethylbenzene at 3,500 pg/L, xylenes at 2 1,000 pg/L, and MTBE at 210,000 pg/L. <br /> The maximum TBA concentration was 2,800 pg/L in PS/MW-15, which is near the <br /> downgradient edge of the plume. PS/WC-4S was sampled in lieu of monitoring well UP/MW-1, <br /> which has been buried by construction activities. <br /> Table 6 in the Annual Report lists the monitored natural attenuation (MNA) results for 2008, <br /> and the text states that petroleum hydrocarbons are currently being degraded under both <br /> aerobic and anaerobic processes. <br /> The Investigation Report states that NuStar advanced 21 borings (NS-1 through NS-21) and <br /> collected soil and groundwater samples from the A through D zones. Three A-zone soil <br /> samples were submitted for laboratory analysis. Seven groundwater samples were collected <br /> from the A-zone, 17 from the B-zone, 10 from the C-zone and 1 from the D-zone. NuStar <br /> believes that zones observed east of the site correlate with shallower groundwater bearing <br /> units beneath the Site. Therefore, they propose to reclassify the units to correspond with <br /> shallower depths. <br /> Soil samples collected in suspected off-site source areas in the vicinity of Stork Road from <br /> depths ranging from eight to 11 feet bgs had maximum TPHg and TPHd concentrations of <br /> 1,300 milligrams per kilogram (mg/kg) and 370 mg/kg, respectively. These borings contained <br /> no MTBE above detection limits and low concentration of BTEX. Based on these findings, <br /> NuStar determined that these areas could no longer be considered source areas for the <br /> groundwater plume in the.Site vicinity. <br /> The highest concentrations of TPHd were observed in grab groundwater samples from C- and <br /> D-zone boring NS-11 at 54,000 pg/L and 29 pg/L, respectively. Elevated TPHd concentrations <br /> were also present in groundwater samples obtained from NS-7, NS-3, NS-14, and NS-21. <br /> Elevated concentrations of TPHg were found in grab groundwater samples from the A through <br /> D zones in borings NS-5, NS-8, NS-9, NS-12, NS-18, and NS-19. The highest grab <br /> groundwater concentration of TPHg was observed in a C-zone sample collected from NS-8 at <br /> 28,000 pg/L. These locations generally correlated with the highest concentrations of BTEX <br /> compounds. The highest grab groundwater detections of MTBE and TBA occurred at NS-5 <br /> and NS-1 in the reclassified A/B zone at 1,700 pg/L and 2,100 pg/L, respectively. <br /> NuStar's evaluation of the groundwater data states the following: <br /> • MTBE concentrations increase with depth from the shallowest water bearing zone to about <br /> 50 feet bgs. <br /> • There appears to be a channel of coarser grained material facilitating the spread of <br /> benzene and MTBE. <br /> • The elevated concentrations of TPHd observed in NS-21 indicate the presence of an off- <br /> site source that is unrelated to the MacSteel facility since no clear pathway exists to the <br /> D-zone. <br />