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Mr Joe Aldridge - 2 - 19 August 2006 <br /> ST Services Stockton Terminal <br /> J <br /> • attempt to advance borings in the C-zone (67 to 80 feet deep) using direct push drilling <br /> technology; if the laboratory analytical results indicate that the dissolved phase constituents <br /> in groundwater originated at the NuStar facility, <br /> • use a different drilling technology. possibly hollow-stem auger or sonic. if refusal in the C- <br /> andor D zone is encountered using direct push technology, <br /> • submit soil samples for laboratory analysis. and <br /> • install groundwater monitoring wells in the C- and D-zones, if necessary. <br /> NuStar has conducted monitoring at the Site since 1992. In 2002. gasoline releases occurred <br /> from aboveground storage tanks (AGTs) G 3301 . G 3302. and D 1503. Groundwater <br /> monitoring at the Site is conducted pursuant to Monitoring and Reporting Program (MRP) No <br /> R5-2007-0818. Regional Water Board staff reviewed the 22 July 2008 Groundwater <br /> Monitoring Report. Second Quarter 2008 (Second QMR). <br /> The source area monitoring well. ST/MW-1 . has historically contained SPH. ST/MW-1 was not <br /> included in the quarterly monitoring program until 2005, when no SPH was observed. During <br /> the second quarter of 2008, this well contained the maximum concentrations of TPHg, <br /> benzene, toluene. ethylbenzene, and MTBE at 160.000 micrograms per liter (ug/L). 16.000 <br /> pg/L, 8.100 pg/L. 3.300 pg/L, and 180.000 respectively. PS/MW-14 also contained SPH until <br /> 2005 The highest concentration of TPHd was detected in PS/MW-14 at 7.700 pg/L. NuStar's <br /> efforts to use global positioning satellite (GPS) and an excavator to locate monitoring wells <br /> UP/MW-1 and UP/MW-3 proved unsuccessful Therefore. NuStar will continue to sample <br /> PS/WC-4S to allow collection of data in this area. <br /> Our comments are presented below. <br /> . The Revised VVork Plan was designed to make investigation of the C- and D-zones <br /> contingent on whether soil and groundwater pollution encountered offsite originated at the <br /> NuStar facility However. the Revised Work Plan does not specify how NuStar intends to <br /> identify the origin of SPH or dissolved product encountered during the investigation <br /> Therefore. I contacted Ms. Spencer by telephone for clarification on the criteria that will be <br /> used to make this determination In our discussion. which was documented in the attached <br /> 8 August email (Email), Ms. Spencer stated that the presence of automotive facilities east <br /> of Stork Road were potential off-site source areas. While advancing borings in the vicinity <br /> of these facilities. NuStar proposes to apply the following lines of evidence to determine <br /> whether petroleum hydrocarbons encountered during the investigation originated off-site of <br /> the NuStar facility. <br /> • The presence of separate phase hydrocarbons (SPH) based on visual observations <br /> and/or field sheen tests in A-zone soil in the borings located east (or on) Stork Road or <br /> upgradient of the facility; <br /> • elevated petroleum concentrations (indicative of the presence of SPH) in A-zone soil in <br /> the borings located east (or on Stork Road or upgradient of the facility: <br /> • a pattern and distribution of soil and groundwater concentrations in the A- and B-zones <br /> that support the presence of an off-site source. and/or <br /> • composition of the fuel compounds in soil or groundwater in off-site borings. <br />