Laserfiche WebLink
zone, capillary fringe and upper portion of the saturated zone. Due to the presence of <br /> adsorbed contamination and the limited access to the subsurface, in-situ chemical <br /> oxidation can often be among the most cost effective remedial options. <br /> Disadvantages: The effectiveness of this technology is sometimes dependent upon <br /> permeability of the subsurface soils which are primarily clay-rich. <br /> Discussion: Based on this review of site conditions, including depth of impacted soil <br /> and groundwater with a significant dissolved phase concentration of TPHg and BTEX, <br /> in-situ hydrogen peroxide and/or sodium persulfate injection is considered a viable <br /> option for this site. The capability of remediating the hydrocarbons and treating the <br /> vadose, capillary fringe and upper saturated zones within a rapid time frame are <br /> particularly well suited to the existing conditions and requirements. Bench testing will <br /> provide detailed information regarding site-specific degradation rates. This technology <br /> involves the in-situ injection of chemical oxidants through 2 to 4-inch diameter wells or <br /> Geoprobe drill rods to treat the contaminants of concern in the source area. <br /> Through the application of ISCO technology, the material reduction of COCs in the <br /> groundwater will be achieved to the best achievable cleanup levels that is economically <br /> feasible. The best achievable cleanup level will be established through bench scale <br /> testing and pilot application and agreed upon with LARWQCB before application of the <br /> f1 full scale remediation effort. Based on previous case studies, reductions of TPH-g in <br /> soil and groundwater, BTEX compounds can be reduced from 25% to 75% with one <br /> injection event, however, specific site conditions and site variables will affect results. <br /> These variables affecting delivery of the treatment chemicals include the amount of <br /> total organic carbon (TOC), metals and other competing reactions that will consume the <br /> chemical oxidant, alkalinity, pH, and effective porosity. <br /> 7 <br />