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C L E A k <br /> G R O U P <br /> Environmental SCrvIces <br /> appropriate for reducing concentrations of aromatic and Iighter hydrocarbons associated with <br />' gasoline, in unstratified sediments of moderate to high permeability Further, the infected oxygen <br /> partitions to a dissolved-phase and can enhance the aerobic biodegradation of contaminants <br />' Generally, this option is always operated with S VE to capture and treat vapors escaping from the <br /> groundwater <br />' The results of the pilot study performed at the site indicate that AS as essential if SVE technology <br /> is to be successful at this site During pilot testing air flow rates improved more than 100% with <br />' AS, from 8 5 cfm at a applied vacuum of 40 an w c to 22 4 cfm at the same applied vacuum <br /> The only drawback to AS as a groundwater remediation option is that it does not exert hydraulic <br />' control over the dissolved-phase plume Recent groundwater momtonng results indicate that the <br /> plume indeed appears to be stable and mostly limited to the area of the site Further, fuel has not <br />' been dispensed at the site since at least 1992 when the UST system was removed Therefore, <br /> plume control does not factor heavily in selection of a clean-up technology for this site <br /> Additionally, although experience suggests that AS is effective at removing light to mid range <br /> gasoline hydrocarbons (i e BTEX) from the dissolved-phase, it may have difficulty achieving <br /> non-detectable dissolved-phase TPHg concentrations This option would also require the <br />' installation of several AS wells (Figure 7) <br />' 6 3 2 Groundwater Extraction and Treatment <br /> Groundwater extraction and treatment has been proven as an effective means of controlling <br />' contaminant migration and reducing contaminant levels Although dissolved concentrations can <br /> be reduced through groundwater extraction, this method generally will not bring dissolved <br />' contaminant concentrations to below the stringent clean-up levels identified However, once <br /> asymptotic concentrations are reached, further reduction an concentrations generally slow down <br /> considerably, and natural attenuation becomes the primary process of contaminant reduction <br />' The chemical properties of gasoline range hydrocarbons suggest that groundwater extraction for <br /> contaminant mass removal alone is ineffectual It as a more useful technology an situations with <br />' MTBE contamination, because it is more soluble than gasoline hydrocarbons but has a higher <br /> Henry's Constant, making an-situ volatilization difficult However, MTBE is not a contaminant <br />' of concern at this site The greatest benefit of groundwater extraction comes from exerting <br /> hydraulic control over a migrating plume and lowering the water table to expose soil to the <br />' effects of vapor extraction <br />' ZB 3 78C CAP 15 November 24,2002 <br />