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Ms. Wendy Cohen <br /> 19 December 1994 <br /> Page 2 <br /> All chromatographs of samples with detectable concentrations of TPH by Method 8015 will be <br /> submitted with the analytical results for review by the RWQCB-CV. Thus, the hydrocarbon <br /> range for the purgable compounds will be reported along with a quantification of the total <br /> extractable hydrocarbons. <br /> Additionally, CPL proposed that the following analytical methods be omitted from the MRP: <br /> Constituents Units Sample Test Method Sampling <br /> Preparation Frequency <br /> TPH as Gasoline mg/l 5040/50302 Modified 8015 Quarterly <br /> TPH as Kerosene mg/l 5040/50302 Modified 8015 Quarterly <br /> TPH as Diesel No. 2 mg/l 5040/50302 Modified 8015 Quarterly <br /> TPH as Diesel No. 4 mg/l 5040/50302 Modified 8015 Quarterly <br /> Total Recoverable mg/l 5520F/3513 EPA 418.1 Quarterly <br /> Petroleum Hydrocarbons <br /> Oil and Grease mg/l 5520B3 552013/664 Quarterly <br /> Total Lead mg/l 3020 7421 Quarterly <br /> 1. A chromatographic standard shall be developed for each constituent. <br /> 2. Purge and trap method used for sample preparation. <br /> 3. Extraction method used for sample preparation. <br /> These analyses should be omitted from the MRP because: <br /> • The petroleum hydrocarbons at the site have been fingerprinted as crude oil. <br /> • Standards used for quantifying TPH as gasoline, kerosene, and diesel no. 2 & 4 are not <br /> applicable, since these quantifications are reported as refined products. <br /> • Method 8015 Modified using a crude oil standard quantifies hydrocarbons from <br /> approximately C8 to C40, thus analysis by TPH as gasoline, kerosene, and diesel no. 2 & 4 <br /> would be redundant. <br /> • Methods 418.1 (TRPH) and 5520B/664 (O&G) are non analyte-specific analytical <br /> techniques susceptible to multiple positive interferences from non-petroleum sources. <br /> • Crude oil generally does not contain lead. Lead was a common additive to gasoline in the <br /> past, however, gasoline is not present at the Dividend site. Therefore, the analysis for <br /> total lead is not applicable to this project at this time. <br /> CPL will perform the next round of quarterly groundwater sampling upon your authorization <br /> (either verbal or written) of the proposed revisions to the MRP. <br /> It was stated in the cover letter to the DRAFT MRP that a work plan to evaluate the lateral <br /> and vertical extent of petroleum hydrocarbons in soil and groundwater is required. It is the <br /> position of CPL that both the lateral and vertical extent of hydrocarbon impacted soil and <br /> groundwater is defined on the Dividend Property. However, in order to adequately monitor <br /> the impact to groundwater at the site, CPL proposes the abandonment of groundwater <br />