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J A <br /> Page 5 <br /> CRA MEMORANDUM <br /> VOCS <br /> The LCS/LCSD contained all compounds of interest. All LCS recoveries and RPD's were within the <br /> laboratory control limits,demonstrating acceptable analytical accuracy and precision. <br /> TPH <br /> The LCS/LCSD contained representative crude oil compounds. All LCS and RPD recoveries were within <br /> the laboratory control limits,demonstrating acceptable analytical accuracy and precision. <br /> MATRIX SPIKE/MATRIX SPIKE DUPLICATE(MS/MSD)ANALYSES-ORGANICS <br /> To evaluate the effects of sample matrices on the extraction or digestion process,measurement procedures, <br /> and accuracy of a particular analysis,samples are spiked with a known concentration of the analyte of <br /> concern and analyzed as MS/MSD samples. The RPD between the MS and MSD is used to assess analytical <br /> precision. If the original sample concentration is significantly greater than the spike concentration,the <br /> recovery is not assessed. <br /> MS/MSD analyses were performed as specified in Table 1. <br /> VOCS <br /> The MS/MSD samples were spiked with all compounds of interest. All percent recoveries and RPD values <br /> were within the laboratory control limits,demonstrating good analytical accuracy and precision. <br /> FIELD OA/OC SAMPLES <br /> The field QA/QC consisted of one(1)trip blank sample,one(1)equipment blank sample,one(1)field <br /> blank sample and one(1)field duplicate sample set <br /> Trip Blank Sample Analysis <br /> To evaluate contamination from sample collection,transportation,storage,and analytical activities,the trip <br /> blank was collected and submitted to the laboratory for VOC analysis. All results were non-detect for the <br /> compounds of interest. <br /> Equipment and Field Blank Sam l�alysis <br /> To assess field decontamination procedures,the equipment and field rinse blank was submitted for <br /> analysis,as identified in Table 1. All results were non-detect for the analytes of interest <br /> Field Duplicate Sam 1p e Anal <br /> To assess the analytical and sampling protocol precision,the field duplicate sample was collected and <br /> submitted "blind"to the laboratory,as specified in Table 1. The RPDs associated with these duplicate <br /> samples must be less than 50 percent for water. If the reported concentration in either the investigative <br /> sample or its duplicate is less than five times the reporting limit(RL),the evaluation criteria is one times the <br /> RL value for water. <br /> All field duplicate results were within acceptable agreement,demonstrating good sampling and analytical <br /> precision. <br />