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Jbe Lentini • - 3 - 2 February 2010 <br /> Former Pipelines, Tracy <br /> in the Central Valley Region. The Basin Plan assigns drinking water as a potential <br /> beneficial use (BU) of to all groundwater underlying the Central Valley. As such, cleanup <br /> standards must be derived pursuant to drinking water standards. The Basin Plan states <br /> that groundwater shall not contain taste- or odor-producing substances in concentrations <br /> that cause nuisance or adversely affect BUs. The Central Valley Water Board's July 2008 <br /> A Compilation of Water Quality Goals may be used to assign numerical values that <br /> implement the narrative objectives. If background concentrations are below WQOs, the <br /> cleanup goals for COPCs in groundwater are set by background concentrations. <br /> Cleanup levels for soil and soil vapor are not set by any specific set of screening levels in <br /> the Central Valley. They are site specific and are determined by the maximum <br /> concentrations that prevent the degradation of groundwater quality and risk to human <br /> health. Soil cleanup levels that are protective of groundwater quality may be calculated <br /> using the Central Valley Water Board's June 1989 Designated Level Methodology for <br /> Waste Classification and Cleanup Level Determinations (DLM). Cleanup levels for soil <br /> vapors may be evaluated using modeling software, such as VLEACH, which is available on <br /> the internet at http://www.epa.gov/ada/csmos/models/vleach.html.. <br /> 2. Shell is free to perform the proposed risk assessment, but Central Valley Water Board staff <br /> will require Shell to clean up soil and groundwater pursuant to the requirements of the <br /> Basin Plan, not to the screening levels proposed to the RA Work Plan. If Shell chooses to <br /> proceed with the RA, the cleanup goal for each affected media would be the most stringent <br /> concentration of either the Basin Plan WQOs or the RA in order to protect both water <br /> quality and human health. <br /> 3. The RA Work Plan also proposes to conduct soil vapor sampling from permanent soil <br /> vapor probes. It is unclear whether permanent soil vapor probes have already been <br /> installed at the site or if Shell intends to propose their installation. <br /> 4. Page 2 of the Addendum states that soil and groundwater samples will be collected from <br /> the two deepest borings and provides a description of the proposed laboratory analytical <br /> suite. We understand that selected soil samples will be also be analyzed for geotechnical <br /> parameters including hydraulic conductivity, pore fluid saturation, porosity, bulk density, <br /> moisture content, organic content, and grain size. Neither the MW Work Plan nor the <br /> Addendum clearly define the criteria that will be applied to select the soil samples that will <br /> be submitted for laboratory analysis. In addition, in response to our 28 January2010 <br /> emailed inquiry requesting clarification on the sampling plan, CRA indicated that <br /> groundwater sampling for laboratory analysis will be restricted to the sentinel boring. <br /> It is unclear from which borings soil and groundwater samples will be sent for laboratory <br /> analysis. Soil and groundwater data from both deep borings may be essential to whether <br /> there is a nexus between the former pipeline and any potential groundwater contamination <br /> below 150 feet bgs. In addition, geotechnical data may be needed from more than one <br /> location to be representative of actual site conditions. Shell needs to submit the criteria, in <br /> writing, that will be used to determine which soil samples will be submitted for laboratory <br /> analysis and specify the minimum number of soil and groundwater samples that could be <br /> submitted for analysis. <br />