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ME <br /> RIM WM <br /> "M <br /> MINES, <br /> the catalytic rt.,actor, from theve ports are an- <br /> alyzed to de LernlrW tIls-, )IydroCabon dc-atroCtion efficiencler.. <br /> 01)CRATInG Pf:RF0qMANC1' <br /> Vapor concentrations from two project situ are shown in <br /> Figure 2. Tlic data illustrate the broad range of vapor <br /> composition!; under which the WX is capable of operating. <br /> The top curve nhovl- data from an operation during which the <br /> extracted vapor was In the flammable range. (The lover <br /> Mimmability limit of ganoline vapors In air Is about 15,000 <br /> ppm(v), or 1.5t(vl). Thv. lower curve shows data obtained <br /> during operaLlon of a CAR unit. At the beginning of this <br /> project, the extract.(,(] air had a high Combustible content <br /> and dilution air was required to prevent overheating of the <br /> catalyst. The admixture of dilution air resulted in a <br /> slower drawdown of the hydrocarbon concentration for the <br /> first 20 days. <br /> Potential eminnionn to the atmosphere without control of the <br /> vented gas are shown In Fiqure 3. At the 10,000 ppmtv) <br /> level and a flow rate of 100 cin, the emir cions would be <br /> almost 400 poupidper day. ' The VCP unit with supplemental <br /> , <br /> fuel would be the recommended operating node at this concen- <br /> tration of hydrocarbon,,. Emissions from the VCP have been <br /> measured by numerous regulatory agencies such as the San <br /> Diego APCD, South Coast AQMD, and the California Air <br /> Resources Board. In all instances the hydrocarbon des- <br /> truction efficiencies have been above 99.81. Thus actual <br /> hydrocarbon emissions from the stack are less than 1.0 <br /> lb/day. CO levels have been below 10 ppm, and NOX levels <br /> have been below I ppm. Lead and sulfur have not been <br /> detected. <br /> At the 3,000 ppn(v) level and a flow rate of 90 cfm, the <br /> uncontrolled emissions would be 100 lb/day. Operating a <br /> catalytic reactor at 90t destruction efficiency would reduce <br /> the emissions to TO lb/day. It would be possible to operate <br /> the catalytic reactor at a higher destruction efficiency, <br /> thereby reducing emissions below 10 lb/day. This could be <br /> done by raising the temperature of the catalyst bad. There <br /> Is a trade-off, however, between catalyst bad temperature <br /> and catalyst life. we recommend-that-the catalytic reactor <br /> be-operated-3n a cost-effective <br /> way to meet emission gu C- <br /> lines while, at the same time, minimizing catalyst deteri- <br /> oration. At recommended operating conditions the catalyst <br /> life has been found to exceed one year. <br /> EMi55ions from operations in the CAR mads~ are shown in <br /> Table 1. The data art- abstracted from a report submitted to <br />