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Stantec <br /> L & M OPERABLE UNIT- FOURTH QUARTER AND ANNUAL 2010 SITE STATUS, <br /> REMEDIAL SUMMARY, AND GROUNDWATER MONITORING REPORT <br /> Summary of 2010 Annual Monitoring and Sampling <br /> January 31, 2011 <br /> 5.10 2010 ARSENIC TRENDS <br /> In accordance with the MRP for the Site, groundwater sampling for the presence of arsenic was <br /> not required during the 2Q10 and 4Q10. Arsenic concentrations in selected shallow and deep <br /> zone wells within the hydrocarbon plume and within perimeter wells were evaluated for historical <br /> trends on a semi-annual basis during the 1Q10 and 3Q10. During 2010, arsenic detectable <br /> concentrations ranged from 0.0078 (MW-23; 1Q10) to 0.34 mg/L (MW-19; 1Q10) in the shallow <br /> zone wells, from 0.0080 mg/L (MW-35; 1Q10) to 0.086 mg/L (MW-59; 3Q10) in the B-Zone <br /> wells, from 0.0070 mg/L (MW-61; 3Q10) to 0.031 mg/L (MW-54; 3Q10) in the C-Zone wells, and <br /> from 0.011 mg/L (MW-70; 1010) to 0.040 mg/L (MW-55; 3Q10) in the D-Zone wells. Arsenic <br /> concentrations over the past three years appear to be relatively stable. Graphs depicting <br /> arsenic trends in selected shallow and deep zone wells within the petroleum hydrocarbon plume <br /> (shallow wells MW-9, MW-32, 2AMW-13, DPE-9, and deep zone well MW-17) and shallow and <br /> deep well pairs along the perimeter of the dissolved plume (MW-34/MW-35, MW-25/MW-26, <br /> and MW-27/MW-28) are included in Appendix F. Arsenic trends will continue to be evaluated <br /> during the 1 Q1 1 and 3Q11. <br /> 5.11 2010 ANNUAL SITE SUMMARY <br /> Groundwater elevations, groundwater gradient, and chemical concentrations throughout 2010 <br /> were generally consistent with historical data. The area of greatest impact to groundwater by <br /> petroleum hydrocarbons, in the shallow zone wells, is centered in the vicinity of well 2AMW-14 <br /> and the DPE wells, which have consistently reported the presence of SPH. Petroleum <br /> hydrocarbon impacts and SPH in this area are currently addressed with the operation of the <br /> DPE/ASVE/SVE system. The area of greatest petroleum hydrocarbon impact within the deep <br /> zone wells is found off Site in the southern section of the Water Front Towers' parking lot, in <br /> wells MW-43, MW-47, MW-48, MW-49 and MW-50, and in the northern section of the L&M OU <br /> site, in wells MW-17 and MW-52, which have contained measurable SPH or sheen since their <br /> installation. SPH in this area is currently addressed with quarterly (at a minimum) extraction <br /> events. The shallow impacted groundwater plumes are generally delineated to the south, west, <br /> and north by the current well network and the Deep Water Channel. The deeper impacted <br /> groundwater plumes are generally delineated to the south and west. Additional assessment is <br /> needed to define the plumes originating east of the Site at the UOU and MOU. <br /> All accessible petroleum hydrocarbon-impacted soil has been removed from the L&M OU and <br /> off-site to the north in the Water Front Towers' parking lot as a result of pipeline removal and <br /> soil over-excavation activities conducted on behalf of the L&M OU Group, except for a small <br /> portion of impacted soil that remains beneath the on Site remediation compound which existed <br /> prior to excavation activities. Additional assessment and remedial activities have also been <br /> performed by the SRDA to address contaminated soil and remaining pipelines east of the site at <br /> the UOU and MOU, and north of the site to the west and north of the Waterfront Towers parking <br /> lot. The results of the UOU and MOU excavations are included in Treadwell and Rollo's <br /> Removal Action Completion Report Unocal Operable Unit on Area 2A dated August 5, 2009 and <br /> the results of the excavation north of the site and to the west and north of the Waterfront Towers <br /> parking facility are in Wallace Kuhl's Underground Storage Tank Removal Report Former North <br /> Edison Street dated June 8, 2009. <br /> I:\Tidewater\TW Stockton(Parcel 2A-0415)\Reports\QMR\2010\4010-Annual\4Q10 and Annual OSSRQRSRQMR Stockton_FINAL.doc 5.8 <br />