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Dolly Madison/Langendorf Bakery - 2 - 4 April 2008 <br /> 1426 S. Lir coin St., Stockto` <br /> The HHRH incorporated the data reported in the PIER into HHRH sections of data evaluation, <br /> exposure assessment, toxicity assessment, risk assessment, conclusions, and <br /> recommendations. An executive summary provides an abstract for the HHRH, concluding that <br /> cancer risk is equal to or below the 10-6 (one in one million) range that is generally acceptable. <br /> Likewise the total non-cancer risk is below the hazard index of 1 that is generally considered <br /> acceptable. As a result of these conclusions, a workplan was not submitted. <br /> The HHRH Section 2 Data Evaluation states "...not all of the data are appropriate for use in a <br /> quantitative risk assessment...Total petroleum hydrocarbon measurements, such as GRO <br /> (gasoline range organics, AKA total petroleum hydrocarbons as gasoline, or TPHg, represent <br /> mixtures of chemicals that, because of their highly variable composition, do not have descriptive <br /> health criteria. Therefore, the toxicity of these mixtures is best described by the aggregate <br /> toxicity of key individual chemicals of the mixture, such as BTEX(benzene, toluene, <br /> ethylbenzene, and xylenes). For the purpose of this evaluation, and as is the practice in <br /> California (Cal-EPA 1994), TPH measurements were not included directly in the data evaluation <br /> process." The HHRH states xylenes and toluene were selected as chemicals of potential <br /> concern (COPCs) for soil vapor, while groundwater and soil COPCs included BTEX, tertiary <br /> butyl alcohol, methyl tertiary butyl ether, ethyl tertiary butyl ether, tertiary amyl methyl ether and <br /> 1 ,2-dichloroethane. <br /> Comments <br /> 1. Evacuating TPHg results for soil and soil gas is the current practice in California, using <br /> the surrogate toxicity values methodology for the carbon ranges associated with <br /> gasoline, which are accepted by this office. The comparison TPHg surrogate toxicity <br /> values are available in the literature. Specifically, the San Francisco Bay Regional Water <br /> Quality Control Board's Environmental Screening Levels (ESLs), in their Screening For <br /> Env,ronmental Concerns at Sites with Contaminated Soil and Groundwater dated <br /> November 2007 (available from their website) discusses the methodology and provides <br /> references. However, the PIER states that TPHg and other constituent results detected <br /> in soil and soil gas did not exceed the ESLs Tier 1 levels. Had the TPHg exceeded the <br /> ESLs, we would have required a Tier 2 or Tier 3 Risk Assessment for TPHg, using the <br /> methodology outlined above. <br /> 2. As stated above, the proposed PIER addendum will be submitted with updated results of <br /> soil gas and groundwater monitoring from new wells in S. Lincoln St., which were <br /> delayed due to negotiations for access agreements with the City of Stockton. Note that <br /> any new soil gas results need to be compared to the November 2007 ESLs, and if they <br /> excE�ed the ESLs, a Tier 2 or Tier 3 (as appropriate) risk assessment will be required for <br /> the iew data. <br /> 3. The CAO requires that the PIER include a Workplan for additional assessment, if <br /> necessary, and a "...Problem Assessment Report (PAR) which includes information from <br /> the ,mplementation of the Workplan and sufficient detail on the nature and extent of the <br /> discharges of waste to provide a basis for future decisions regarding subsequent cleanup <br /> and abatement actions." not an addendum to PIER. As stated above, the required <br /> schedule was not included in the PIER for implementation of the Workplan. Per the <br />