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I Shell Distribution Facility, Stockton -3- 23 March 1995 <br /> Hydrocarbon contaminants reported at Shell during 1994 include diesel, gasoline, the gasoline <br /> components benzene, toluene, ethylbenzene, and xylenes (BTEX), and dissolved lead. The <br /> analytical methods used by Shell's laboratories are in accord with the recommendations of the Tri- <br /> Regional Staff Guidelines. Some of the analytical detection limits that were reported seem high; <br /> perhaps due to high levels of concentrations and matrix interferences. The various analytes are <br /> non-uniformly distributed across the site, as shown in Figs 7-10 of the 1994 Annual Report. This <br /> suggests either(or both) differential migration of the plume components, or more than one <br /> plume/source. Several "hot spots" (points of higher than average concentration of one or more <br /> component in one or more sampling round) are shown. The "hot spots" do not coincide, further <br /> suggesting more than one source area. <br /> Some of the analytes are reported as "lighter than" or"heavier than" diesel, or"atypical" diesel. I <br /> do not know whether these reports mean that one or more additional, unspecified hydrocarbon <br /> components may be present, or that chemical alteration (weathering or degradation) of the diesel <br /> has occurred. Lastly, separate phase hydrocarbons are reported from several of the wells, in <br /> thicknesses up to .73 inches. <br /> Although all of the above information regarding contaminant distribution may be gleaned from <br /> examination of the text figures and the analytical reports in the 1994 Annual Report, it is not <br /> discussed in the narrative. <br /> Remedial Actions: <br /> Until April 1993, Shell was using three of the shallow monitoring wells (wells 1, 23, and 24) as <br /> extraction wells Extracted water was stored onsite in tanks and periodically trucked to the Shell <br /> refinery in Martinez for treatment. The extraction system was shut down when limitations were <br /> placed on the amount of water that could be handled by the refinery. Shell obtained a permit to <br /> discharge treated ground water to surface water in June 1994, and the ground water extraction was <br /> resumed November 29, 1994. <br /> Shell has submitted a Remedial Action Plan (RAP) which included initiation of a soil vapor <br /> extraction system(SVE). A pilot study for the SVE, completed in August 1994, found that SVE <br /> technology is appropriate for the site. An air discharge permit for the SVE, required from the San <br /> Joaquin County Air Pollution Control District, is pending. The SVE system was installed during <br /> the fourth quarter, 1994, but is not yet operating. <br /> Cleanup and Abatement Order 94-705 requires startup of the GWE and SVE systems by <br /> 1 December 1994. The Order also requires that Shell obtain all necessary local and state permits <br /> before beginning work, a requirement that they have violated in failing to obtain timely approval <br /> of the Air District permit for the SVE. The Order further requires that Shell ensure that the GWE <br /> completely capture the plumes (i.e., show zero lines of contamination in all water bearing zones). <br /> Sampling must show that the extraction is successful. If noncontainment is confirmed, Shell is <br /> required to submit, within 30 days of receiving the sample results, a Contingency Plan to mitigate <br /> the condition. <br /> In response to results of geoprobe studies conducted offsite in September, 1994, and in January <br /> 1995, Shell has proposed installation of two new ground water monitoring wells, MW-28 and <br />