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i • <br /> Oxidation Pond Conversion -2- 18 December 1990 <br /> Sharpe Site <br /> concentrations to laterally and vertically characterize the unsaturated zoneprior to <br /> the proposed conversion. The lateral locations were selected based on the boring <br /> locations that had previously shown the highest concentrations of heavy me als and <br /> heavy oils. Two borings will be installed at the northern end of the pond iear the <br /> inlet (locations J and K) , one boring will be installed in the central portion <br /> (location N) and one boring at the southern end of the pond (location T) , Two soil <br /> samples will be collected from each boring to provide the vertical characterization of <br /> the residual waste concentrations. One soil sample is to be collected within the upper <br /> foot and the other is to be collected within two feet of the current ground water <br /> table. <br /> The waste constituents of concern for the soluble analyses are the heavy metals of <br /> arsenic, barium, cadmium, chromium, lead, vanadium and zinc and heavy oils, <br /> specifically lubricating oils (Method 8015 Modified), total petroleum hydrocarbons <br /> (TPH) and oil and grease (0&G) . The specific heavy metals were selected baseo on the <br /> 1988 and 1990 total concentrations which showed elevated concentrations Of these <br /> constituents above background concentrations. VOCs were not considered for Onalysis <br /> because they had previously not been detected within soil samples collected wi hin the <br /> pond soil samples. The soil samples need to be analyzed for soluble concentrations to <br /> determine whether the waste constituents pose a threat to water quality. T e Waste <br /> Extraction Test (WET) , using either dilute citric acid or dionized water as the <br /> extraction solution, was discussed. A citric acid extraction solution is used when <br /> there are acidic conditions. It was decided that the citric acid would be used for the <br /> WET. <br /> Potential remedial measures were discussed. The method of cleanup of the oxidation <br /> ponds will be determined based on the analytical results of the soluble analy es. If <br /> it is determined that there are soluble residual waste constituents in the uns turated <br /> zone, then excavation of the "hot-spot" areas within the oxidation pond, conf rmation <br /> sampling and backfilling may be needed as a remedial measure prior to the pond <br /> conversion. Bioremediation was also considered as a remedial measure for cleanup, but <br /> may not be a viable alternative because of the metals concentrations. If the <br /> analytical results of the soluble analyses indicate that the waste constituents are not <br /> soluble and the concentrations are at background levels, then the pond conversion may <br /> proceed without any remedial measures because it will have been determined hat the <br /> residual soil contamination does not present a threat to water quality. <br /> Because the storm water retention basin will not have a five foot separation between <br /> the base of the pond and the highest known ground water level and because the total <br /> concentrations of the residual waste constituents indicate that there m y be a <br /> potential threat to water quality, it was decided that a soil bentonite liner flay need <br /> to be installed in the storm water retention basin. Although a sample from the first <br /> major storm event of the wet season is preferred, Sharpe plans to collect a sample of <br /> the storm water runnoff from this season as a preliminary waste character izati on. The <br /> storm water runoff should be analyzed for VOCs, Title 22 metals, Modified 8015, TPH and <br /> 0&G. If the waste characterization indicates that the storm water runoff is a waste <br /> then the structure would need meet the classification and siting criteri under <br /> Sections 2510, 2530 and 2540 of Chapter 15. If it is determined that the sto m water <br /> runoff is not a waste, then the land disposal criteria under Chapter 15 would not be <br /> applicable because the runoff would not represent a threat to water quality. <br /> The design of the storm water retention basin is to be based on a 100 year flooc event. <br /> Sharpe indicated that they would prefer a 70 percent expansion of the current o idation <br />