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ADVISORY—ACTIVE SOIL GAS INVESTIGATIONS <br /> volume testing may be warranted to determine the air permeability of the subsurface <br /> (see Appendix D for more information). <br /> 4.2.4 Additional Purge Volume Tests <br /> Additional purge volume tests may be warranted by site-specific situations. Under the <br /> following conditions, additional purge volume tests should be conducted: <br /> • A previously unknown lithology is encountered; <br /> • Variable flow conditions are unexpectedly encountered; or <br /> • If the default purge volume of three is used and a VOC of concern not previously <br /> detected is subsequently detected. <br /> If a new purge volume is selected, then 10 percent of the previously completed soil gas <br /> wells should be re-sampled using the new purge volume. Re-sampling may be <br /> necessary for all previously sampled soil gas wells depending on results of the re- <br /> sample. The soil gas investigation may then be continued with the revised purge volume <br /> in the remaining areas. <br /> 4.3 PURGE/SAMPLE FLOW RATE AND APPLIED VACUUM <br /> Flow rates between 100 to 200 milliliters per minute (mL/min) and vacuums less than <br /> 100 inches of water should be maintained during purging and sampling to minimize <br /> stripping (partitioning of vapors from pore water to soil gas), to prevent ambient air from <br /> diluting the soil gas samples, and to reduce variability between contractors. Maintaining <br /> these flow rates and vacuums will increase the likelihood that representative samples <br /> will be collected. A flow rate greater than 200 mL/min may be used when purging times <br /> are excessive, such as for deep wells with larger-diameter tubing. However, a vacuum <br /> of 100 inches of water or less must be maintained during sampling whenever a higher <br /> flow rate is used. The pressure gauge used to measure vacuum should be calibrated <br /> and in good working order. <br /> A vacuum gauge should be used between the soil gas sample tubing and the soil gas <br /> purging device to verify that 100 inches of water or less is maintained during sampling. <br /> Gas-tight syringes may also be used to qualitatively determine if a high vacuum soil <br /> condition is present. If a high vacuum condition is present due to low permeability soil, <br /> the sampling technician can feel the suction while the plunger on the syringe is being <br /> withdrawn. If low permeability conditions are encountered where 100 inches of water is <br /> exceeded, the well can be sampled using the techniques in Appendix D (Soil Gas <br /> Sampling in Low Permeability Soil). <br /> 4.3.1 Vacuum Pump <br /> When a vacuum pump is used, collect samples on the intake side to prevent potential <br /> contamination from the internal parts of the pump. To collect the sample in a polymer <br /> gas sampling bag, a lung box'is required. Record the vacuum readings and <br /> ' A lung box is a small airtight chamber into which the polymer gas sampling bag is placed. The connective tubing to <br /> the bag protrudes out a hole in the chamber. The sealed chamber is evacuated by a pump, causing the bag to <br /> April 2012 20 <br />