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Ground Zero Analysis, Inc. <br />HEALTH AND SAFETY PLAN <br />JOB HAZARD ANALYSIS AND SUMMARY <br />Chemical Hazards <br />TASK(S) <br />CHEMICAL <br />PEL/STEL/IDLH <br />KNOWN <br />SIGNS/SYMPTOMS <br />(SOIL, WATER, <br />CONCENTRATION <br />AIR, ETC.) <br />29,000 ppm (soil) <br />Headache; nasal, eye, skin and <br />1,2,3 <br />TPH gasoline <br />None Established <br />51 ppm (water) <br />respiratory irritation drowsiness, <br />fatigue, pneumonitis, nausea, <br />asphyxia, CNS depression. <br />PEL 0.1 ppm (NIOSH)/ <br />Irritation of eyes, nose, respiratory <br />I ppm (OSHA) <br />56 ppm (soil) <br />sys; giddiness, headaches, nausea, <br />1,2-3 <br />Benzene <br />STEL l ppm (NIOSH)! <br />3.3 ppm (water) <br />staggered gait, fatigue, anorexia, <br />5 ppm (OSHA) <br />lassitude, dermatitis, human <br />IDLH 3,000 ppm <br />carcinogen. <br />Fatigue, weakness; confusion, <br />PEL 100 ppm <br />1,500 ppm (soil) <br />euphoria, dizziness, headache; dilated <br />I ._. <br />Toluene <br />STEL 150 ppm <br />pupils, tearing, nervousness, muscular <br />IDLH 2,000 ppm <br />11 ppm (water) <br />fatigue, insomnia, paresthesia, <br />dermatitis. <br />Ethylbenzene <br />PEL 100 ppm <br />STEL 125 ppm <br />380 ppm (soil) <br />Irritation of eyes, mucous membranes; <br />IDLH 2,000 ppm <br />3 ppm (water) <br />headache, dermatitis, narcosis, coma. <br />Dizziness, excitement, drowsiness, <br />PEL 100 ppm <br />1,800 ppm (soil) <br />incoordination, staggering gait, <br />1,23 <br />Xylenes <br />STEL 150 ppm <br />14 ppm (water) <br />irritation of eyes, nose, throat; corneal <br />IDLH 10,000 ppm <br />vacuolization; anorexia, nausea, <br />vomiting, abdominal pain; dermatitis. <br />Irritation, nausea, vomiting, and <br />0.1 ppm (soil) <br />diarrhea, and central nervous system <br />1._.3 <br />MTBE <br />PEL 50 ppm (ACGQ) <br />0.0012 ppm (water) <br />(brain) effects similar to alcohol <br />intoxication; liritation to the nose, <br />throat, lungs and respiratory tract. <br />Eye irritation, headache, confusion, <br />PEL ] 0 m <br />PP <br />Not known (soil) <br />excitement, malaise (vague feeling of <br />discomfort), nausea, vomiting, <br />I _ _ <br />Naphthalene <br />STEL 15 ppm <br />0.62 ppm (water) <br />abdominal pains, bladder irritation, <br />IDLH 250 ppm <br />profuse sweating, jaundice, blood in <br />urine <br />PAGE <br />