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�- LUPEROX DEL`Tp► 9 <br /> Material Safety Data Sheet <br /> ATOFINA Chemicals, Inc. <br /> 10 STABILITY AND REACTIVITY <br /> Stability <br /> This material is chemically unstable and should only be handled under specified condition& See HANDLING <br /> e1VAD .:)TORAGE section of this MSDS for specifiec conditions. <br /> SART -Self Accelerating Decomposition Temperature. Lowest temperature at which the tested package size <br /> will undergo a self-accelerating decomposition reaction. This reaction will generate flammable vapors which <br /> may autoignite. The length of time tc generated a decomposition reaction, after the SADT has been reached <br /> or exceeded, is dependent upon how much the SADT has been exceeded and the length of time needed for <br /> the reaction exotherm (heat spike from increasing decomposition rate) to initiate a rapid decomposition <br /> reaction. Typically, SADT is inversely proportional to package size. Larger packages will have a lower SADT <br /> due to smaller ratio to heat transfer area to volume of product. <br /> Hazardous Polymerization <br /> Does not occur. <br /> Incompatibility <br /> Contact with strong acids, alkalis, oxidizers, transition metal salts, promoters/accelerators, & reducing agents <br /> may result in a violent decomp reaction or in product degradation. (see SECTION 16) <br /> Hazardous Decomposition Products <br /> Temperatures at or above the SADT can result in the release of hazardous decomposition products which are <br /> flammable and may autoignite. <br /> 11 TOXICOLOGICAL INFORMATION <br /> Toxicological Information <br /> Data on this material and/or its components are summarized below. <br /> Methyl ethyl ketone peroxide(s) <br /> Single exposure (acute)studies indicate that this material (40-60% in dimethyl phthalate) is moderately toxic to <br /> rats if swallowed (LD50 484 mg/kg), slightly toxic to rabbits if absorbed through skin (LD50 4,000 mg/kg), <br /> practically non-toxic to rats if inhaled (4-hr LC50 17-50 mg/1), corrosive to rabbit eyes, and moderately irritating <br /> to rabbit skin (4-hr exposure, 4.5/8.0). <br /> Following an allergic skin reaction in a paint sprayer, patch testing produced an allergic skin reaction with this <br /> material as well as other components of the paint. However, subsequent patch testing did not produce allergic <br /> skin reactions in 34 healthy subjects. Swallowing of this material was reported to cause liver injury in one case <br /> report. <br /> Repeated oral administration of this material was reported to result in decreased body weight, mild liver and <br /> kidney injury and death in rats. Following repeated application of this material in dimethyl phthalate to the skin <br /> of rats and mice, severe skin damage and animal deaths (only at the highest dose levels)were the primary <br /> effects. Spleen and bone marrow changes considered secondary to the severe skin damage were noted in <br /> animals at the high doses. Higher doses applied to rat and mouse skin for a shorter time produced similar <br /> effects. Long-term repeated skin application of this material in dimethyl phthalate was reported to enhance <br /> skin tumor production in mice irradiated with UVB. This material has produced genetic changes in standard <br /> tests using bacterial or animal cells. However, no genetic changes occurred in a standard test using animals. <br /> —Product Code: 114000 y�ffi:Y- Revision: 3 issued:16 FEB 2001 Page 5 of 10 <br />