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Material Safety Data SheetNo.317
<br /> Genium Publishing CorN'E
<br /> poration Rup
<br /> TOLUE
<br /> 1145 Catalyn Street (Recision D)
<br /> Scheneclady,NY 12303-1836 USA Issued:August 1979
<br /> (518)377-8855 Cunnu pl nLSWHG[ARP.
<br /> Revised: April-1986
<br /> SECTION 1. MATERIAL IDENTIFICATION 20
<br /> MAT;: hV" : TOLUENE li�,ls
<br /> 3
<br /> wr L)FSJ �'ATIO?`5: Methyl Bcnzcne,Methyl Bcnml,Phcoylmca=c,Toluol, F 3 2 D
<br /> C7Hg,CAS#0106-86-3
<br /> R:0
<br /> MAN'UFACTtrRFRlSUPPLIER: Available from many suppliers,including: PPE* R 1
<br /> Allied Corp.,PO Box 2064P„Morristawa,NJ 07960;Tcicphooc:(20l)455-;407 See sect 8
<br /> 1 3
<br /> Ashland Chemictl Co.,Industrial Chemi Wis k Solvents Div.,PO Box 2219, S 2
<br /> Columbus,OH:Tclephonc:(614)669-3644 R A
<br /> SECTION 2. INGREDIEN'T'S AND HAZARDS coo .. HAZARD DATA
<br /> Toluene ca 100 84r TLV:1DO ppm,or
<br /> C"3 375 nVm3'(Skin)"
<br /> Man,Inhalation,TCLD:
<br /> 100 ppm Psychotropic'
<br /> -------------------
<br /> ' Current(1985-86)ACGIH TLV,The OSHA PEL is 200 ppm with an Rat,Oral,LD50 5406 mgrrcg
<br /> a=plable ceiling conceotradoo of 3D'3 ppm and an acceptable Ra[,Inhalation,LCLo:
<br /> maximum peak of 500 ppuJ10 minutes. 4DOD ppm/4 hrs.
<br /> Skin designation indicates 11rat toluene can be absorbed L'nrough intact Rabbit,Shin,LD50:14 gmTI;
<br /> shin and contribute w overall exposure.
<br /> :,• A1fecLs the mind. Human,Eye: 300 ppm
<br /> .SECTION 3. PHYSICAL DATA
<br /> BoWrg Point...23]'F(111'C) l:vaporadno Pate(BnAc=1)...2.24
<br /> 112por Pressure C 20'C,=Hg...22 Specific Gravity(H2O=1)...0.866
<br /> Walcr Solubility,C 20'C,wt.%...0.05 Melting Point...-139'F(4s'C)
<br /> Vapor Densiry(Air-1)...3.14 Percent Volatile by Volume...ea 140
<br /> Molecular Weight...92.15
<br /> Ar�cz znc-and odor, Clear,colorless liquid with a chzracteristic ammalic odor. The odor is detectable to most individuals in
<br /> the ranee of 10 to 15 ppm. Because olfactory fatigue occurs rapidly upon exposure to tolucoe,odor is not a good warning
<br /> property,
<br /> SECTION 4. FIRE AND EXPLOSION DATA LOWER I UPPER
<br /> Flash Point and Method Autoigniuon Temp. Flamrnabiliry Limits In Air
<br /> 407(4'C) CC f 8967(480*0 %by Volume 127 7.1
<br /> E X71-'Q aEffI�y M Ef I : Carbon dioxide,dry chemical,alcohol foam. Do not use a solid stream of water b:zause the srrcam
<br /> will scat:rr and spread the fire, Use water sp:ay to coal taaLVcontainers that are exposed to fire and to disperse vapors.
<br /> 1'41210 10 F Fe yp t ti ZLRM This OSHA class 13 flarmnzbl:liquid is a dangerous fir:ha=--d It is a moderate fire
<br /> hzzard whrn exposed to oxidizers,hear,spari:s,or open flarne. Vapors arc hcavicr than sir and may travel a.Josiderablr,
<br /> distance to an ignition source and flash back.
<br /> SP=CI.A1 F7R.E•Fl:+-THIN.FgCr— zl 1P.E5: Fuc fighters should wear self-contained breathing apparatus u-i h full facepic e
<br /> o,m—,d iz a posilive-pressure mode when fighting furs involving toluene.
<br /> SECTION S. REACTIVM' DATA
<br /> r u=r,r e,t It rnti<7�rjg}i ln•t;,,5: Toluene is stable in close.,containers a=.room temperature under normal storage any
<br /> `andbog conditions. It docs not undergo ha—tous polymcriza ion. This material is�=mpaftle with strong oxidizing
<br /> arenu,dinluogcn ictaoxidc,silver perhlnratc,t �anl�nmctn:i:,and w-z7iunt hcxafluo:ide. Contact with these materials
<br /> tiro)'cause fire or explosion. hit-ic acid and mlucno,especial])-ta the presence of sulfuric acid,will produce nizated
<br /> eomp:runds tha:ace danficrousiy explosive.
<br /> :Mp DrrinNe_Tr)-VOIb: Avoid exposure to sparks,open flzmt,hot surf:,ces,and all sources of heat and ignition. Toluene
<br /> will attack some fomes of plastics,rubber,end coatings. Thermal dccomposition or burning produces carbon dioxide andlor
<br /> carbon monmidc.
<br /> - Com.-iT.i e I BSc r�+�^.hfWwy Gmw.�
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