|
�ma.,l^4 vsaaa.xw�ctxxr^�ax>xw:ry
<br /> s ,
<br /> ga
<br /> Y
<br /> No. 317 4186 TOLUENE
<br /> SECT]01 6. HEALTH HAZARD INFORMATION IT]A'
<br /> I0ucrc U 110:C0n513C.LC t CLMUIOgen r..UK f.I I', 0:U-):--h. '.'%- , 'L": tiCpna Oi .ucac rt=y Caw-
<br /> i.•ri:suon of Or eves,most,upper respiratory tract,and stir.. Exposu:e to_{:'1'7.--.[or F.hD=eausCs rrdld fauguC,
<br /> wealµcss,Confusion,lacrimation(tearing)and pamsthcsia(a scns4on of pricLling.LngfinF,or-rccPinE.or the Min]hat
<br /> has no obicctive taus). Expasu n to higher conccnt.—Lioas ma+ cause hc:wtjzhc,tlausc2�d1::loess,dilatrL pupils,and
<br /> euphaaa,and,in scaert cases,may cause unzonsciousncss tad dca h. The liquid is iM aung to the eyes rued sl:,in. Cor:a:-t
<br /> with the eves may cause crasicnt mmcal dwnagc,cnaiunctival iritatioc,an_bt ros if net pro ap ly tumovc . Rcp ated
<br /> andrer proEvngcd con :kith the sk r. nay e use drying aad era=l:.ing. It ray b=absort ed through the sl is in toxic
<br /> amounts. ]ngcsdoa causes'rrilzuoa Of Ghc g.sunintcstioal lra:l z'td clay case effects rtscrnblinp thos fm n inhalatico of
<br /> LhC va;ra:. Chronic o-•-trcxNsurc 10 tolucrc may cause reversible ktdni:y and lrv'cr injury. ' L-Z_j.1D: ,. `a tiL :
<br /> lmmediaLely flush cvcs,imludinp undo ryclids,with oa ring water for::leas: 15 rsi,utc'. Gni medical at:Cntloa if trntaLon
<br /> persisu.• C6,74 C'f: 3nL^tc'iaCly'flush sl'a(fvr at Icas: 15 m:nutcs)w:tilc rtmoving can, .iraLed slots=)d
<br /> clothing. Wzsh exposed zrca kith soap and water. Get medical z•,-njor is irnL.tiot persists or if a la-Tc arra has been
<br /> exposed.* l"Ar ATIn : Remove victim to fresh rir. Rcstoro endFor sup:v:brunNriF:s rccuircd.Keep viairn warm and
<br /> quit:.Ge:mcdi=ai help.' ll, EE T IQ : Give victim 1 to 2 Flasscs of waw:o:milia.Contact t poison con=1 ecntc.. Do nc:
<br /> Lnziucc vomi'^g unless dire:ted to,do so.Tr_ispor victim to a r rind fa lin'.Etre:Five a_nvtring b; motif' to a Nmon
<br /> who is un=ms:ious or convulsing. •GET MEDICAL ASSISTANCE- In plc^;paw trnedi:,community. Oct medical help
<br /> for fu:hc:Lrta nicn4 obscrvL'Joa,and sup,*;:a.'tcr firs:aid,if indicated.
<br /> SECTION 7. SPILL. LEAD. ANM DISPOSAL PROCEDURES
<br /> cult_l 11--4v: fib'f; szrc:v p rsoanei of large spills or Iccj.s. Remove ali sou:xs of heat end ignition. T-rrvidc maxicrum
<br /> explosion-proof vcnQation. Lmil metes to spin z.-Ca to nc=sst:�'personnel only. pemave Laking co.na2inc.n to safe
<br /> place if fersiblc, Cleanup pasoanel need protection agiav:contact with licuid ad inhz]asoa of vapor(SLC sat S).
<br /> Si=LIMSL.I_: Absorb small s7M5 wiL'I pzlvcr[novel o:ve:mioulitc.Co tin large spills and collect if feasible,or
<br /> absorb MLh vermiculite o:sand. Plazc waste soivcn:o:absorbent into closed containers fn:disposal asinF oaaspai=S
<br /> tools. Lsouid can be flushed with+valet to nn open holding arca to:handling. Do mot flush to sewer,watclshcd,o:wztcrw•ay.
<br /> 4! rt, : Plazc in suitzbie containCr for disposal by a beers-coa=tor c.bur]in an approvcd incincra or.Consider
<br /> reclaiming by disti:lation.Contaminated absorbent can b=bu icd in a saniLzr'1zndfill. Follow all Fedc;ai,s:atc, and local
<br /> rtgulztions. ILm 9-5:103-10 ppm. Toluene is designated as a h":z dous wzsle b;'tete EPA. Ter.EPA(RCRA)lift'No.is
<br /> U?20(40 CFR 261). Tire itportable gtlzsttity(PQ)is 10r'1hs14L kF(40 Crt? 11 rr.
<br /> SECTIONS. SPECIAL PROTECTION 1NFORMAT1ON
<br /> provide geeeral znd lar-A exhaust ventllaaon to meet TL`,'recut oats.vcnt:lEaa iras and other elczzin�s:n'icc must bC
<br /> nonspa ring and have an explosion-proof design. Exhzus:hcwds should have a face volocity of at 1cas:100 Irm(line=:fee:
<br /> Y-;t-,:-lute)aad be dcstg-aCd to CEP tare h-%vy veaor. For e rcrgc;cy o:na W o a:expoi;=s when i:'r TLV=y 1:'ezccadcd,
<br /> use as mgraic chemi.ai CL—ndge respirator if ceoccnLr's:ion is less than 2P3 ppm End as app aved caaiste,-Fes msl.or sLlf-
<br /> coatain:d brczti i z appz:asus ui:h full fz,cpiczz if conxn:ratioa is pc.=:hxn 207 pp=
<br /> Safer•glasses o:splash goggles should be worn in all cork z_s. Nceprcnt gloves,z�mn,fact shield,booLs,and baht
<br /> appropciar±protective elo thing Pad equipment should be avauzbic m s zod worm necessan'to prevent alar Q eye coma
<br /> Remove eont.=:nated elolning immediately and do not wez it until it has been pmcrly laundered.
<br /> Eyewash stations zyd safery shnvvcrs should bC rt39ily zvzE n:c in use rad hradung acus.
<br /> C0nt2::leases pose a special itazz-d;soh lenses may zbso.b i':i:z:u and all lenses coo==1e ihc=
<br /> SECTION 9. SPECIAL PRECALTIONS AND COMME't"I'S
<br /> SIQLAQC viaro in a cool,dry,wcL'-venuat-' arta away f-Dm oxidaing agents,hca,sparks,o:open Oamc,
<br /> Storage r_zzs mu:mrw:OSHA rcrlul:cmcoLt for Class M fia.:.mablc liquids.Use mCtal safery cans for handling small amounts.
<br /> eoaainers from physio dzau:gc, Us=only with adeyuaLe vcz0?6on.Avoid c=a�'t with eyes,shin, o:Clnthdng.Do
<br /> rat 1'711.1,L Or:agent USC cauluon when handlitlF C-ds enmpeucd because it can bc zbsorr'throuph intact skin in toxin
<br /> w:,ea,^,:5. C^=^IG__ .^'T_�r r'�':'C_T'ni•L(:= G.-mmd,aor M:.d =:al wn:,mors z d G:L'r:men:10 prevent static sl::Is k'?•
<br /> =ZI=F n•aasfer. ':.Aa no:smolt iv use v:sa.gc a-czs.Us=noaspa.-LinF tools, CLlti;tint S: P epi_ omen:
<br /> . d pc odic m diem Cxa_c:-?azizing the Live.,1_idn-ys,.nervus systr;11_g<_,ham-,aad bloc s-ault be provide.'..
<br /> ,Workers cx?oscd COr.:C ra=o^s gm-Lter than talc anon levci (5r,,ppm)should M cxz=Xt d a:1=a_C oa'-C a vca:,lice Of
<br /> ai ahoi C=P^,,g:ayate L.'Ic tox::CitC=o: :011ier=.
<br /> +'•`�`'`_'r_= ""C• Em ..;cc:=.�u-s con ,:.x:::..,r•si'.._.. ]:z,::iv....,,rc �,v.�
<br /> Toluene is dcsi~aa—z a ht ou_ subs:..-.cc by L=_.,r(=n C=E illy. �D i Clzssifi:z on:Fi_r.:ab:c hgtFd. UtC1'S.
<br /> Dva cod 16.2,1.2 1 :L zC E n. c1: l
<br /> . J'1C}'0.2L'S n L'L^.t['_:fS''••�c!_:o-:�r9cc trete_tc:nd r.:./+t:�i:�";K+a App rovzlJF 7;.7,
<br /> ■:�OlShct'.'..lt.�.^.r•G'12:S-5;1�::'l.T^G'L:0 L't'1w; tCi50^.?:r[Ll:
<br /> .-- — ------------rex txeaakei:stre:ce:.._-�ov .—z:on�feL:.:-.t .:ci
<br /> Lt-1 -- 'L E.r�.�` --- - --- - /- -------------------------------------
<br /> . W.-W.Lowe-i-_u.is i�__:c.-a::�:o:s a�C esa�-res ac rs:U_t:a.::::z. ❑ LIS:. }'r s'
<br /> tat'mLO Nn:a-,i_ ()' t
<br /> �:cLRae p'�-pows onto:ca��©:.es c:,nuc ` �1�j C{i1 g31 nPt'lt1y �� r 1 •� ;nom
<br /> - ti.,csrnc�:wvn,c-v:.r.-_v::nr.c.._-r..;•c�,.c�r. p�.r nw - Cllr
<br />
|