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• Erratic pattern and low concentrations of VOC detections. Landfill gas conditions <br /> can fluctuate significantly depending on the available biomass and refuse moisture <br /> conditions. A liquid-phase release typically results in more consistent VOC <br /> detections and concentrations. <br /> • Listing of detected VOCs. The listing of VOCs associated with a liquid-phase release <br /> is often restricted to only few analytes. The VOC listing for the FSL is relatively <br /> extensive and includes fuel-product compounds such as benzene, toluene, and xylene, <br /> as well as chlorinated solvents such as DCE, TCE, and PCE. The presence of freon <br /> compounds such as dichlorodifluoromethane and trichlorotrifluoromethane are also <br /> considered key gas indicators. <br /> • Historical concentration of VOCs near upgradient wells MW-5A and MW-513. The <br /> groundwater gradient at the site is generally from south to north, and these 2 wells <br /> were located adjacent to Little John Creek, upgradient of WMU-B. <br /> • Absence of notable inorganic impacts. As described in the 1999 and 2000 Annual <br /> Monitoring Reports (Kleinfelder& Associates, 1999 and 2000), the inorganic <br /> groundwater quality measured in downgradient monitoring well samples is quite <br /> similar to upgradient groundwater quality conditions. The exceedences of inorganic <br /> concentration limits are considered minor and representative of natural variation in <br /> groundwater chemistry rather than a release from the facility. <br /> 4.0 POTENTIAL IMPACTS <br /> The potential impacts associated with the low-level VOC impacts to groundwater <br /> adjacent to the FSL appear small. Low-level VOC detections at the FSL were evaluated <br /> in the past in a groundwater modeling project that was completed by Kleinfelder& <br /> Associates (1991). Kleinfelder's work was completed in response to low concentrations <br /> of VOCs that were detected adjacent to U-B in monitoring well MW-5A, and <br /> included preparation of a RCRA Facility Investigation(RFI). The RFI considered a <br /> point-source release of VOCs near the southern border of WMU-B (near wells MW-5A <br /> and MW-5B), and concluded that offsite migration of VOCs was unlikely. <br /> Recognizing that modeling a source for the VOC release near the southern boundary of <br /> WMU-B was not a conservative assumption, LSA&Associates oversaw a modification <br /> of Kleinfelder's model by Geotechnical Research &Development(GRD) during <br /> development of the Environmental Impact Report (EIR) for expansion of the site (LSA, <br /> 1993). The GRD revision placed the source for VOC impacts near the eastern boundary <br /> of the site (i.e., near the downgradient border of the landfill). The GRD model concluded <br /> that the only VOCs that might reach the nearest offsite well (9690 S. Austin Road) were <br /> benzene and cis-1,2-DCE, and that the concentrations of these constituents at the offsite <br /> well location would be significantly less than ARARs. <br /> As indicated in Table 1, the property(and well) at the nearest offsite well (9690 S. Austin <br /> Road) is now owned by Forward Inc., and bottled water is delivered to the tenants that <br /> reside there. As indicated in quarterly monitoring reports, and as summarized on the <br /> (electronic) tabulated monitoring results, other than methylene chloride (a common <br /> laboratory contaminant)no VOCs have been detected in samples from wells at 9621 and <br /> 7 <br /> Geologic Associates <br />