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groundwater monitoring wells were sampled by Del-Tech between March 29 and 31, <br /> 2010. Both surface water stations were sampled on March 31, 2010. <br /> Samples were collected from each sample point with sufficient liquid and submitted to <br /> BC for analysis of the parameters stipulated in RWQCB Order No. R5-2003-0049. Table <br /> 2-1 presents the monitoring schedule and summarizes the analytical methods utilized <br /> during the current monitoring period. Water quality samples were also analyzed in the <br /> field for dissolved oxygen, turbidity, temperature, specific conductance, and pH and <br /> recorded on well data sheets. The groundwater monitoring wells and leachate were <br /> sampled in accordance with the sampling and analysis procedures detailed in Appendix <br /> B. The well data sheets,raw laboratory data, certificates of analyses, and chain-of- <br /> custody records related to the sampling program are included in Appendix C. Field and <br /> laboratory analyses are summarized in Tables 3-1 through 3-6. <br /> 3.1.2 QA/QC Results <br /> The QA/QC program completed for the first quarter 2010 water quality monitoring event <br /> at the Austin Unit included analyses of three field blanks, two trip blanks, one equipment <br /> blank, three laboratory method blanks, and one duplicate sample. The trip, field, and <br /> equipment were analyzed for VOCs by EPA Method 8260 and method blanks were <br /> analyzed for all required analyses. The results of the QA/QC program indicate that low- <br /> levels of chloroform, chloromethane, methylene chloride, and toluene were measured in <br /> one or more of the QA/QC blanks during the monitoring period. Review of the primary <br /> sample results indicates that similar concentrations of toluene were detected in the <br /> primary samples collected from well AMW-18 and surface water station ASW-2 and <br /> were flagged as suspected field/laboratory contaminants. During the first quarter 2010 <br /> monitoring event, a duplicate sample was collected from CAP well AMW-I and labeled <br /> AMW-DUP. Duplicate groundwater results are presented along with the primary data in <br /> Table 3-2. With the exception of arsenic and vinyl chloride, comparison of the values in <br /> the primary sample with the duplicate indicates that there was good agreement(within <br /> 10%). Of note, concentrations less than the PQL were not included in the comparison <br /> since these are estimated values. <br /> Review of laboratory analysis dates with the required holding times indicates that, with <br /> the exception of hexavalent chromium for well AMW-2, all samples were submitted and <br /> analyzed within the required holding times during the first quarter 2010. The holding <br /> time for hexavalent chromium was exceeded by approximately 19.5 hours. Review of <br /> the analytical data indicates that the hexavalent chromium concentration measured in <br /> well AMW-2 is within the historical range of values measured for this constituent. Based <br /> on the results of the laboratory blank and duplicate analyses, it is concluded that the <br /> laboratory data generated for the first quarter 2010 monitoring period are generally <br /> acceptable and the water quality samples collected from the Austin Unit appear to be <br /> representative of water quality at the site. <br /> D:\2010_0013\FA_IQ10.doc 9 Geologic Associates <br />