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Mr. Kevin T. HaroffAft <br /> Page $ <br /> overstate the amount of small-sized particles present in <br /> the sample." <br /> In its March 3, 1990 analytical report, RJ Lee stated that "the <br /> fine particulate (< ten Am) in the surge bin appears to be shards <br /> and broken pieces." In addition, while manipulating particles with <br /> tweezers for observation under scanning electron microscope, AIHL <br /> noted that the larger particles were brittle and that "these <br /> fragments disintegrated easily whenever picked up by the tweezers. " <br /> None of these techniques subjected the ash to extremes which would <br /> be abnormal to find in actual handling practices. It is, <br /> therefore, reasonable to assume that the particles could be <br /> fractured during routine handling into particles less than or equal <br /> to ten µm (or even five µm) in size, and, from RJ Lee's <br /> observations, it is seen that fracturing does occur. <br /> It is obvious from analysis of the data provided for this ash that <br /> there are severe limitations on the amount of confidence which can <br /> be placed in the data representing concentrations of particle <br /> constituents of the ash. Both sampling techniques and analytical <br /> methods for measuring quantities, types, and sizes of silica <br /> particles produce results which may be subjective. These <br /> analytical methods can underestimate the concentrations of small <br /> sized particles in the ash due to agglomeration of small sized <br /> particles in the bulk samples and adherence of particles to sifting <br /> equipment. Sampling techniques can "lose" smaller particles due to <br /> air dispersal. These limitations are also evidenced by the wide <br /> fluctuations of reported free crystalline silica content of the <br /> ash, ranging from below 0.3 to 62.4 percent. These fluctuations <br /> did not correlate with incineration temperature or any specific <br /> operating parameter, and appeared random. <br /> The Wadham Energy Company has evidently acknowledged that its ash <br /> poses a hazard in its letter of June 16, 1989 warning of the <br /> dangers associated with silica exposure and urging that everyone <br /> coming into contact with the ash be properly protected. Wadham's <br /> MEDS indicates that the rice hull ash presents an inhalation <br /> hazard. It further identifies silicosis as the chronic effect of <br /> exposure, and recommends respiratory protection. <br /> The primary concern regarding the silica present in Wadham's ash is <br /> the hazard posed by inhalation of the particles. It is difficult <br /> to make a correlation between the concentration of respirable <br /> silica particles in the ash to known airborne particulate <br /> thresholds which have been accepted as "safe" or as "no adverse <br /> effect levels." CalOSHA has established an occupational <br /> "permissible exposure limit" (PFL) of 0.05 mg/m for free <br /> crystalline silica, and 0.10 mg/m for amorphous silica. These <br /> thresholds are based on time weighted averages of exposure. <br />