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<br />724060 - Unbranded Gasoline Reformulated with Ethanol Page 4/10
<br />Issue Date: 20-Jun-2016 Status: FINAL
<br />Precautions for safe handling: Obtain special instructions before use. Do not handle until all safety precautions have been read
<br />and understood. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Take
<br />precautionary measures against static discharge. Use only non-sparking tools. Do not eat, drink or smoke when using this product.
<br />Do not breathe vapor or mist. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after
<br />handling. Use good personal hygiene practices and wear appropriate personal protective equipment (see section 8). Extremely
<br />Flammable. May vaporize easily at ambient temperatures. The vapor is heavier than air and may create an explosive mixture of
<br />vapor and air. Beware of accumulation in confined spaces and low lying areas. Open container slowly to relieve any pressure. The
<br />use of explosion-proof electrical equipment is recommended and may be required (see appropriate fire codes). Refer to NFPA-70
<br />and/or API RP 2003 for specific bonding/grounding requirements. Do not enter confined spaces such as tanks or pits without
<br />following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. Do not wear contaminated clothing or shoes. Keep
<br />contaminated clothing away from sources of ignition such as sparks or open flames.
<br />High pressure injection of hydrocarbon fuels, hydraulic oils or greases under the skin may have serious consequences even though
<br />no symptoms or injury may be apparent. This can happen accidentally when using high pressure equipment such as high pressure
<br />grease guns, fuel injection apparatus or from pinhole leaks in tubing of high pressure hydraulic oil equipment.
<br />For use as a motor fuel only. Do not use as a solvent due to its flammable and potentially toxic properties. Siphoning by mouth can
<br />result in lung aspiration which can be harmful or fatal.
<br />The use of hydrocarbon fuel in an area without adequate ventilation may result in hazardous levels of incomplete combustion
<br />products (e.g. carbon monoxide, oxides of sulfur and nitrogen, benzene and other hydrocarbons) and/or dangerously low oxygen
<br />levels.
<br />Gasoline engine exhaust contains hazardous combustion products and has been identified as a possible cancer hazard. Exposure
<br />should be minimized to reduce potential risk.
<br />Static Accumulation Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this material.
<br />To minimize this hazard, bonding and grounding of tanks, transfer piping, and storage tank level floats are necessary but may not,
<br />by themselves, be sufficient. Review all operations which have the potential of generating and accumulating an electrostatic
<br />charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch
<br />loading, filtering, mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. Special care should
<br />be given to ensure that special slow load procedures for "switch loading" are followed to avoid the static ignition hazard that can
<br />exist when higher flash point material (such as fuel oil or diesel) is loaded into tanks previously containing low flash point products
<br />(such as gasoline or naphtha). For more information, refer to OSHA Standard 29 CFR 1910.106, 'Flammable and Combustible
<br />Liquids', National Fire Protection Association (NFPA 77, 'Recommended Practice on Static Electricity', and/or the American
<br />Petroleum Institute (API) Recommended Practice 2003, 'Protection Against Ignitions Arising Out of Static, Lightning, and Stray
<br />Currents'.
<br />Conditions for safe storage: Keep container(s) tightly closed and properly labeled. Use and store this material in cool, dry,
<br />well-ventilated areas away from heat, direct sunlight, hot metal surfaces, and all sources of ignition. Store only in approved
<br />containers. Post area "No Smoking or Open Flame." Keep away from any incompatible material (see Section 10). Protect
<br />container(s) against physical damage. Portable Containers: Static electricity may ignite gasoline vapors when filling portable
<br />containers. To avoid static buildup do not use a nozzle lock open device. Use only approved containers for the storage of
<br />gasoline. Place the container on the ground before filling. Keep the nozzle in contact with the container during filling. Do not fill
<br />any portable container in or on a vehicle or marine craft. Outdoor or detached storage is preferred. Indoor storage should meet
<br />OSHA standards and appropriate fire codes.
<br />"Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such
<br />containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. "Empty" drums should
<br />be completely drained, properly bunged, and promptly shipped to the supplier or a drum reconditioner. All containers should be
<br />disposed of in an environmentally safe manner and in accordance with governmental regulations. Before working on or in tanks
<br />which contain or have contained this material, refer to OSHA regulations, ANSI Z49.1, and other references pertaining to cleaning,
<br />repairing, welding, or other contemplated operations.
<br />SECTION 8: Exposure controls/personal protection
<br />Chemical Name ACGIH OSHA Phillips 66
<br />Gasoline TWA: 300 ppm
<br />STEL: 500 ppm
<br />Carcinogen 0.5 ppm TWA8hr
<br />0.25 ppm TWA12hr
<br />2.5 ppm STEL
<br />Skin
<br />Toluene TWA: 20 ppm TWA: 200 ppm
<br />Ceiling: 300 ppm
<br />20 ppm TWA8hr
<br />Xylenes (o-, m-, p- isomers)TWA: 100 ppm
<br />STEL: 150 ppm
<br />TWA: 100 ppm
<br />TWA: 435 mg/m3
<br />100 ppm TWA8hr
<br />100 ppm TWA12hr
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