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_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 724060 - Unbranded Gasoline Reformulated with Ethanol Page 5/10 Issue Date: 20-Jun-2016 Status: FINAL 150 mg/m3 STEL Skin Ethyl alcohol STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 Carcinogen --- Benzene TWA: 0.5 ppm STEL: 2.5 ppm Skin TWA: 10 ppm TWA: 1 ppm STEL: 5 ppm Ceiling: 25 ppm Carcinogen 0.5 ppm TWA8hr 0.25 ppm TWA12hr 2.5 ppm STEL Skin Carcinogen n-Hexane TWA: 50 ppm Skin TWA: 500 ppm TWA: 1800 mg/m3 50 ppm TWA8hr 25 ppm TWA12hr Skin Ethylbenzene TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 Carcinogen 20 ppm TWA8hr 10 ppm TWA12hr Skin Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. Engineering controls: If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits, additional engineering controls may be required. Eye/Face Protection: The use of eye protection that meets or exceeds ANSI Z.87.1 is recommended to protect against potential eye contact, irritation, or injury. Depending on conditions of use, a face shield may be necessary. Skin/Hand Protection: The use of gloves impervious to the specific material handled is advised to prevent skin contact. Users should check with manufacturers to confirm the breakthrough performance of their products. Depending on exposure and use conditions, additional protection may be necessary to prevent skin contact including use of items such as chemical resistant boots, aprons, arm covers, hoods, coveralls, or encapsulated suits. Suggested protective materials: Nitrile Respiratory Protection: Where there is potential for airborne exposure above the exposure limit a NIOSH certified air purifying respirator equipped with organic vapor cartridges/canisters may be used. A respiratory protection program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed whenever workplace conditions warrant a respirator's use. Air purifying respirators provide limited protection and cannot be used in atmospheres that exceed the maximum use concentration (as directed by regulation or the manufacturer's instructions), in oxygen deficient (less than 19.5 percent oxygen) situations, or under conditions that are immediately dangerous to life and health (IDLH). If benzene concentrations equal or exceed applicable exposure limits, OSHA requirements for personal protective equipment, exposure monitoring, and training may apply (29CFR1910.1028 - Benzene). Other Protective Equipment: Eye wash and quick-drench shower facilities should be available in the work area. Thoroughly clean shoes and wash contaminated clothing before reuse. Suggestions provided in this section for exposure control and specific types of protective equipment are based on readily available information. Users should consult with the specific manufacturer to confirm the performance of their protective equipment. Specific situations may require consultation with industrial hygiene, safety, or engineering professionals. SECTION 9: Physical and chemical properties Note: Unless otherwise stated, values are determined at 20°C (68°F) and 760 mm Hg (1 atm). Data represent typical values and are not intended to be specifications. Appearance: Clear to amber Flash Point: < -49 °F / < -45 °C Physical Form: Liquid Test Method: (estimate) Odor: Gasoline Initial Boiling Point/Range: 81 - 437 °F / 27 - 225 °C Odor Threshold: No data Vapor Pressure: 330-775 mm Hg @ 100°F / 37.8°C pH: Not applicable Partition Coefficient (n-octanol/water) (Kow): No data Vapor Density (air=1): >1 Melting/Freezing Point: No data Upper Explosive Limits (vol % in air): 7.6 Auto-ignition Temperature: 833 °F / 445 °C Lower Explosive Limits (vol % in air): 1.4 Decomposition Temperature: No data Evaporation Rate (nBuAc=1): >1 Specific Gravity (water=1): 0.68-0.78 @ 60ºF (15.6ºC) Particle Size: Not applicable Bulk Density: 5.66-6.50 lbs/gal Percent Volatile: 100%Viscosity: No data Flammability (solid, gas): Not applicable Solubility in Water: Approximately 10%