Laserfiche WebLink
Work Plan for Additional Site Assessment <br /> and Interim Remediation/Feasibility Testing <br /> ARCO Facility No.5469 <br /> Stockton,California <br /> Page 4 <br /> To evaluate the downgradient extent of the dissolved phase petroleum hydrocarbons and <br /> oxygenates, Delta proposes to install a well cluster (MW-11 and MW-12) to the east of <br /> the site (see Figure 3). In addition, Delta proposes to install a well adjacent to GZA well <br /> MW-11 (screened between 53 and 73 feet bgs) to assess the lateral extent of impact in the <br /> upper sandy unit. The shallow wells will be screened between 35 and 55 feet bgs to <br /> monitor the upper sandy unit. The deeper well will be screened between 60 and 75 feet <br /> bgs to monitor the lower sand unit. <br /> To assess the vertical extent of hydrocarbons beneath the site, Delta proposes to advance <br /> one Cone Penetrometer Test (CPT) boring onsite (see Figure 3) to a depth of 120 feet bgs, <br /> and collect depth discrete soil and groundwater samples. This CPT boring is located <br /> downgr adient of the UST complex and will extend approximately 50 feet deeper than the <br /> base of any well that shows hydrocarbon impact(MW-10). <br /> Interim Remediation/Feasibility Testin <br /> Considering the known vertical and lateral extent of impact to soil and groundwater in the <br /> vicinity of the site, the primary objective of the interim remediation/feasibility testing is <br /> to evaluate an alternative to mitigate the impact originating from the ARCO site, while <br /> not adversely affecting the adjacent plumes. <br /> Delta proposes to initiate interim remediation/feasibility testing to evaluate the results of <br /> ozone injection. Delta proposes to inject ozone (C-SpargerTM) at five locations (see <br /> figure 4) through sparge wells installed to a depth of 55 feet bgs. Review of published <br /> literature indicates that this technology combines the unit operations of air stripping and <br /> oxidative decomposition into a single process. Complete ozonation of petroleum <br /> hydrocarbons should result in formation of carbon dioxide and water. Ozone injection <br /> conducted at low flow rates and pressures, is pulsed on a predetermined cycle. Therefore, <br /> vapor extraction or recovery is not required and there is low risk of groundwater <br /> mounding at the sparge wells. <br /> Given the site geology of silts to clayey silts, relatively flat gradient of 0.0022 ft./ft. <br /> (fourth quarter 2001, sampling event), and the presence of other petroleum hydrocarbon <br /> plumes in the vicinity of the site, Delta does not propose to test conventional remedial <br /> alternatives such as groundwater pumping, soil vapor extraction, and air sparging at this <br /> time. Delta is concerned that conducting a groundwater pump test could potentially draw <br /> contamination from the nearby plumes to the ARCO facility, and therefore is not <br /> proposing a groundwater pump test. Review of the impact to soil samples collected in the <br /> upper 40 feet did not indicate significant impact to warrant remediation of the vadoze <br /> zone. Moreover, the upper 40 feet predominantly consists of clayey silts, which are not <br /> typically conducive to soil vapor extraction. The presence of interbedded sand units, <br /> P:\ARC0154691Work Plan15469 wrkpin 03-2002.doc <br />