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11 <br /> Section 5 Fire and Explosion Hazard- Ivforrnation (,Continue <br /> Special Protective Equipment and Precautions for Fire Fighters : Self-contained MSHA/NIOSH approved respiratory protection and full protective <br /> clothing should be worn when fumes and/or smoke from fire are present. Heat and Flames cause emittance of acrid smoke and fumes. DO NOT RELEASE <br /> RUNOFF FROM FIRE CONTROL METHODS TO SEWERS OR WATERWAYS. <br /> Hazardous Material Identification System (HMIS) Classification National Fire Protection Associate (NFPA) <br /> 0 No significant risk to health <br /> 0 Materials that will not burn <br /> Materials that are normally stable, even 0 <br /> under fire conditions, and will not react <br /> e 0 with water, polymerize, decompose, <br /> condense, or self-react. Non- explosive. <br /> HEALTH = 0, No Hazard beyond that of ordinary combustible materials. <br /> FIRE = 0, Materials that will not burn <br /> INSTABILITY = 0, Normally stable, even under fire exposure conditions, <br /> and are not reactive with water. <br /> Section b. % Accidental R'eleaseNeasures <br /> Personal Precautions, Protective Equipment and Emergency Procedures : Not applicable to nickel alloy in solid state. For spills involving finely divided <br /> particles, clean-up personnel should be protected against contact with eyes and skin. Collect material in appropriate, labeled containers for recovery or <br /> disposal in accordance with federal, state, and local regulations . <br /> Environmental precautions: Not applicable to steel in solid state. Follow applicable federal, state, and local regulations. <br /> Methods and materials for containment and clean up : Collect material in appropriate, labeled containers for recovery or disposal in accordance with <br /> federal, state, and local regulations. Follow applicable OSHA regulations (29 CFR 1910 . 120) and all other pertinent state and federal requirements. <br /> Section 7 Handlin and Storage <br /> Precautions for safe handling: Operations with the potential for generating concentrations above 1/2 the PEL of airborne particulates should be evaluated <br /> and controlled as necessary. Practice good housekeeping. Avoid breathing metal fumes and/or dust. <br /> Conditions for safe storage, including any incompatibilities : Store away from acids and incompatible materials. <br /> Section 8 Exposure Controls / Personal Protection <br /> Component CAS # % wen htl OSHA PEL-TWA ACGIH TLV-TWA <br /> Iroon 100 mg/m3 5 .0 mg/m3 ; A42 <br /> oxide] (Fe) 7439 - 89 - 6 60 88 . <br /> [I <br /> Alloying Elements [fume] [dust & fume] <br /> 0 . 5 mg/m3; A4 <br /> 1 .0 mg/m3 [metal] [metal & Cr (III)] <br /> 0. 5 mg/m3 [Cr (III)] <br /> Chromium3 (Cr) 7440-47- 3 10 - 30 3 0. 05 mg/m3 • A1;BE1 <br /> (Metal) 5. 0 µg/m (Cr (V!)] [Water'-Soluble Cr (VI) compounds] <br /> 2. 5 µg/tn3 [Cr (VI)] 0. 01 tng/m3 ; A2 <br /> Action Level [Insoluble Cr (VI) compounds] <br /> 1 . 5 mg/m3 ; A5 <br /> 0. 5 mg/m3 [metal] [elemental] <br /> Nlckel3 Ni 7440- 02- 0 0 - 46 3 0 . 2 mg/m3 ; Al <br /> ( ) 0 . 1 mg/m [Insoluble <br /> (Metal) compounds] [Insoluble compounds] <br /> 0. 1 mg/mg3 ; Al <br /> Nickel subsulfide <br /> 0 .02 mg/m3 ; A4 <br /> Manganese0 .2 mg/m3 [respirable fraction] [respirable fraction] <br /> (Mn) 7439 -96- 5 0 - 15 3 3 <br /> [elemental & inorganic cpds] 3 mg/m STEL 0 . 1 mg/m ; A4 <br /> Inhalable fraction <br /> 10 . 0 mg/m3 <br /> 10.0 mg/m3 [total dust] [inhalable] <br /> Molybdenum (Mo) 7439-98-7 ` 8 3 .0 mg/m3 [respirable] 3 .0 mg/m3 <br /> [respirable] <br /> 0 .2 mg/m3 <br /> Copper3 (Cu) 7440- 50- 8 < 6 0 . 1 mg/m3 [fume) [fume] <br /> 1 .0 mg/nn3 [dust & mist) 1 .0 mg/m3 <br /> dust & mist <br /> Titanium <br /> 3 (Ti) 13463 - 67 - 7 < 6 15 .0 mg/m3 [total dust] 10 mg/m3 ; A4 <br /> [metal & dioxide] [dust] <br /> Carbon (C) 744044-0 < 2 N /A N /A <br /> 4 PSM -SDS-SS <br /> Rev. Date May - 2015 <br />