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6.1.2 Chemical Degradation <br /> CRS® provides a soluble source of ferrous iron (Fe2+), which, in anaerobic conditions, can <br /> precipitate reduced iron sulfides, oxides, and/or hydroxides capable of destroying chlorinated <br /> contaminants via abiotic chemical reduction. The CRS® can potentially improve the efficiency of <br /> the overall reductive dechlorination process when injected with 3DME (Regenesis, 2017). <br /> 6.1.3 Pilot Test Injections and Monitoring <br /> The injections will be performed in the A-zone beneath the former north pond and adjacent to the <br /> load pad at the south tank farm. The injections beneath the former north pond will occur in three <br /> rows of four points. The rows will be 20 feet apart and oriented perpendicular to the groundwater <br /> flow direction.The injections near the south tank farm will occur in one row of five injection points. <br /> The proposed injection locations are depicted on Figure 8. <br /> The temporary injection points will be constructed using a truck-mounted direct push drilling rig. <br /> The drilling rods will be advanced in the A-zone to 65 feet bgs and then retracted to expose a <br /> screen extending to 45 feet bgs. The 3DME-CRS solution will be injected into the subsurface <br /> through the drilling rods and screen. After the injections are completed, the borings will be tremie <br /> grouted with neat cement through the drilling rods to the surface of the cap in accordance with <br /> San Joaquin County Standards and pursuant to discussions with the RWQCB. <br /> Based on the COC concentrations in groundwater below the former north pond, 5,200 pounds of <br /> 3DME and 2,000 pounds of CRS be mixed with tap water in accordance with the manufacturer's <br /> specifications to create an injection volume of 6,652 gallons (554 gallons per point). At the south <br /> tank farm, 3,200 pounds of 3DME and 1,200 pounds of CRS will be mixed with tap water to create <br /> an injection volume of 3,972 gallons (794 gallons per point). <br /> The solution will be injected into each point at flow rates up to 5 gallons per minute (gpm), and <br /> some points may be injected simultaneously. If needed, low pressure(10 to 40 psi)will be applied <br /> to each point using a specialized well cap and air compressor to ensure maximum distribution of <br /> the substrate to the subsurface without creating preferential flow pathways or flow up the drilling <br /> rods. <br /> New monitoring wells will be installed within and downgradient of the former north pond based on <br /> the pre-2012 and February 2017 flow directions (west to southwest). The wells will be used to <br /> determine if the injections enhance conditions for biodegradation and to monitor COC <br /> concentrations. Groundwater samples will be collected from the surrounding monitoring wells <br /> before and after the injections. <br /> 6.1.4 Performance Monitoring <br /> The enhancement of the environment for microbial degradation will be evaluated by measuring <br /> the parameters shown on Table 3. The groundwater monitoring and sampling program is <br /> summarized in Section 7. <br /> CPS Stockton, California 4 ;Q)"dt <br /> Pilot Test Work Plan <br />