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Attachment B: Data Usability Summary and Laboratory Chemical Analytical Report <br /> Data QC Objectives <br /> SAIC evaluated the project analytical data according to the following parameters in order to <br /> determine their usability: <br /> • Precision <br /> • Accuracy <br /> • Representativeness <br /> • Completeness <br /> • Comparability <br /> Data Usability Summary <br /> The following sections summarize the findings of the data evaluation process. A summary of <br /> qualified data is provided in Table B-1. <br /> Precision and Accuracy <br /> The precision and accuracy of field and laboratory QC samples were evaluated. The calculated <br /> relative percent difference (RPD)of laboratory control samples and laboratory control sample <br /> duplicates(LCS/LCSDs)provided information on the precision of laboratory analyses. <br /> Evaluation of the percent recoveries(%Rs) of LCS/LCSDs and surrogates provided information <br /> on accuracy. All LCS/LCSD %Rs were within the laboratory control limits. All surrogate%Rs <br /> were within the laboratory control limits,with the exception of one sample. The surrogates used <br /> in the analysis for PAHs by EPA Method SW8270C-SIM in field duplicate sample MW-7-WD- <br /> 060504 were below the required laboratory control limits. The laboratory repeated the analysis <br /> and the surrogates were within the control limits,but the required hold time for the sample <br /> extraction had passed. The initial results were reported, and qualified"J"for analytes that were <br /> detected, and"UJ"for analytes that were not detected to note the nonconformance. A potential <br /> low bias is associated with the field duplicate sample results because the surrogate recoveries <br /> were low. The data were not rejected as they are used for qualitative purposes, and the field <br /> sample,MW-7-W-060504, is the sample that will be used for risk assessment. The surrogates <br /> associated with MW-7-W-060504 for PAHs were all within the required control limits. Project- <br /> specific matrix spike and matrix spike duplicate samples were not submitted with the samples. <br /> Field Duplicates <br /> Sample MW-7-WD-060504 is a field duplicate of sample MW-7-W-060504. Field duplicate <br /> RPDs were assessed for analytes detected in both the field sample and field duplicate above the <br /> reporting limit. TPHd and acenaphthene were the only analytes detected above the reporting <br /> limit in both the field and field duplicate sample. The RPD for TPHd was 25 percent,which is <br /> below the control limit of 30 percent. The RPD for acenaphthene was 115 percent,which <br /> exceeds the control limit of 30 percent. The analyte was flagged J in the field sample and the <br /> field duplicate sample to indicate the nonconformance. Phenanthrene was detected in the field <br /> and field duplicate sample,but the concentrations were below the reporting limit and a RPD was <br /> not calculated. Concentrations detected between the method detection limit(MDL)and reporting <br /> limit are estimated and are not used to assess precision. <br /> Representativeness <br /> Representativeness was assessed through the evaluation of method blank samples, trip blank <br /> samples, equipment blank samples, chain-of-custody forms,preservation, and holding times. <br />