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SECTION 6: Accidental release measures <br />Personal orecautions, protective eauiument and emergency procedures R 1 <br />SIMPHOS 23.5P Deflorinated Phosphoric Acid, Feed Grade <br />Safety Data Sheet <br />according to Federal Register / Vol. 77, No. 58/ Monday, March 26, 2012/ Rules and Regulations <br /> <br />2.3. Other hazards <br />No additional information available <br /> <br />2.4. Unknown acute toxicity (OHS US) <br />Not applicable <br />SECTION 3: Composition/information on ingredients <br />Substance <br />Not applicable <br />3.2. Mixture <br />Name Product Identifier % OHS-US classffication <br />phosphoric acid (7664-38-2) ' (CAS No) 7664-38-2 <br />1 <br />Met. Corr, 1, H290 <br />Acute TOx. 4 (Oral), 11302 <br />Acute Tox. 4 (Dermal), 11312 <br />Skin Corr. 16, 11314 <br />Full text of H-statements: see section 16 <br />SECTION 4: First aid measures <br />Never give anything by mouth to an unconscious person. If you feel unwell, seek medical <br />advice (show the label where possible). <br />Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately <br />call a POISON CENTER or doctor/physician. <br />Immediately call a POISON CENTER or doctor/physician. Specific measures (see ... on this <br />label). Wash with plenty of soap and water. Wash contaminated clothing before reuse. <br />Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. <br />Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to <br />do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. <br />Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or <br />doctor/physician. <br />4.2. Most important symptoms and effects, both acute and delayed <br />Symptoms/injuries : Causes severe skin burns and eye damage. <br />Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing significant <br />health hazard. Harmful In contact with skin. <br />4.3. Indication of any immediate medical attention and special treatment needed <br />No additional information available <br />SECTION 5: Firefighting measures <br />5_1. Extinguishing media <br />Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. <br />Unsuitable extinguishing media : Do not use a heavy water stream. <br />5.2. Special hazards arising from the substance or mixture <br />Reactivity : Thermal decomposition generates : Corrosive vapours. <br />5.3. Advice for firefighters <br />Firefighting instructions <br />Protection during firefighting <br />: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any <br />chemical fire. Prevent fire-fighting water from entering environment. <br />: Do not enter fire area without proper protective equipment, including respiratory protection. <br />6.1.1. For non-emergency personnel <br />Emergency procedures : Evacuate unnecessary personnel. <br />6.1.2. For emergency responders <br />Protective equipment . Equip cleanup crew with proper protection. <br />Emergency procedures . Ventilate area. <br />6.2. Environmental precautions <br />Prevent entry to sewers and pubic waters. Notify authorities if liquid enters sewers or public waters, <br />4.1. Description of first aid measures <br />First-aid measures general : <br />First-aid measures after inhalation : <br />First-aid measures after skin contact : <br />First-aid measures after eye contact : <br />First-aid measures after ingestion : <br />01/25/2016 EN (English) <br /> 2/7