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<br />STANDARD PROVISIONS AND REPORTING REQUIREMENTS, JANUARY 2012 - 22 - <br />FOR WASTE DISCHARGE REQUIREMENTS <br />FOR DISCHARGES REGULATED BY SUBTITLE D AND/OR TITLE 27 <br /> <br /> <br />monitoring point, the Discharger may propose to monitor the constituent, at that <br />well, using a concentration-versus-time plot. <br /> <br />41. The Discharger may propose an alternate statistical method [to the methods <br />listed under Title 27, section 20415(e)(8)(A-D)] in accordance with Title 27, <br />section 20415(e)(8)(E), for review and approval. <br /> <br />42. The statistical method shall account for data below the practical quantitation <br />limit (PQL) with one or more statistical procedures that are protective of human <br />health and the environment. Any PQL validated pursuant to Title 27, section <br />20415(e)(7) that is used in the statistical method shall be the lowest <br />concentration (or value) that can be reliably achieved within limits of <br />precision and accuracy specified in the WDRs or an approved Sample <br />Collection and Analysis Plan for routine laboratory operating conditions that are <br />available to the facility. The Discharger’s technical report (Sample Collection <br />and Analysis Plan and/or Water Quality Protection Standard Report), pursuant <br />to Title 27, section 20415(e)(7), shall consider the PQLs listed in Appendix IX to <br />Chapter 14 of Division 4.5 of Title 22, CCR, for guidance when specifying limits <br />of precision and accuracy. For any given constituent monitored at a <br />background or downgradient monitoring point, an indication that falls between <br />the MDL and the PQL for that constituent (hereinafter called a “trace” detection) <br />shall be identified and used in appropriate statistical or non-statistical tests. <br />Nevertheless, for a statistical method that is compatible with the proportion of <br />censored data (trace and ND indications) in the data set, the Discharger can <br />use the laboratory’s concentration estimates in the trace range (if available) for <br />statistical analysis, in order to increase the statistical power by decreasing the <br />number of “ties”. <br /> <br />43. The water quality protection standard for organic compounds which are not <br />naturally occurring and not detected in background groundwater samples shall <br />be taken as the detection limit of the analytical method used (e.g., USEPA <br />methods 8260 and 8270). <br /> <br />44. Alternate statistical procedures may be used for determining the significance of <br />analytical results for common laboratory contaminants (i.e., methylene chloride, <br />acetone, diethylhexyl phthalate, and di-n-octyl phthalate) if part of an approved <br />water quality protection standard. Nevertheless, analytical results involving <br />detection of these analytes in any background or downgradient sample shall be <br />reported and flagged for easy reference by Central Valley Water Board staff. <br /> <br />45. Confirmation of Measurably Significant Evidence of a Release. Whenever <br />a constituent is detected at a detection monitoring point at a concentration that <br />exceeds the concentration limit from the water quality protection standard, the <br />Discharger shall conduct verification sampling to confirm if the exceedance is <br />due to a release or if it is a false-positive (unless previous monitoring has