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15 January 2001 <br /> AGE-NC Project No 96-0232 <br />' Page 11 of 20 <br />' ,ug/l utilizing EPA Methods 8020 and 8260, respectively, MTBE was detected in the 06 December <br /> 2000 grab water sample at concentrations of 350 and 450µg/1, respectively Ethanol was detected <br /> in the 06 December sample at a concentration of 2,600 µg/l The laboratory analysis did not detect <br />' any other constituents of concern Analytical results of pump and treat influent-water samples are <br /> summarized In Tables 2 and 4, laboratory reports are in Appendix F <br />' 7 3 EFFLUENT MONITORING <br /> In accordance with the requirements of Attachment B's Monitoring and Reporting Program to <br /> General Order No 5-00-119, monthly monitoring of the ground water pump and treat efffluent for <br /> flow rate, specific conductivity(EC),pH, temperature, total dissolved solids (TDS),TPH-g, TPH-d, <br />' TPH-mo, BTEX, MTBE, methanol, ethanol, DIPE, TAME, ETBE, TBA, nitrate and total lead was <br /> performed on 30 November and 06, 13, 21 and 27 December 2000, additionally, ground water pump <br />' and treat effluent quarterly sampling for bioassay analysis was performed on 06 December 2000 <br /> Analysis of a grab water sample collected on 06 December 2000 detected nitrate as NO3 in the pump <br />' and treat effluent at a concentration of 40µg/l, temperature was recorded in the laboratory at 19 7 <br /> degrees Celsius, EC at 1,130µmhos/cm, TDS at 690 mg/L and pH at 7 3 Analytical results of nitrate <br /> as NO3 and analysis for EC, pH and TDS are summarized in Table 4 <br />' Laboratory analysis of grab water samples collected from the effluent stream on 30 November and <br /> 06, 13, 21, 27 December 2000 did not detect any petroleum constituents of concern, laboratory <br />' analysis of grab water samples collected on 06 December 2000 from the outlet of GAC media <br /> vessels (GAC-1 and GAC-2) and the outlet of the first SunSolve media vessel (SS-1) did not detect <br /> any petroleum constituents of concern Analytical results are summarized in Table 2 <br />' A bioassay laboratory analysis was performed on a grab sample collected from the effluent stream <br /> on 06 December 2000 The analysis utilized sample factors of 0 ml, 125 ml, 500 ml, 1,000 ml, 1,500 <br /> ml and 2,000 ml Each sample factor was tested with 20 Fathead minnow fish and a"utron volume <br /> of 2,000 ml of di-ionized water, pH, dissolved oxygen (DO) and temperature parameters were <br /> monitored and fish mortalities were counted over 96 hours The bioassay analysis reported a steady <br />' decrease in pH and DO in each sample factor over the 96 hour period, the analysis reported <br /> decreasing pH and DO values with Increasing sample factors Temperature measurements vaned <br /> between 19 5 and 20 5 degrees Celsius The laboratory reported that there were no fish mortalities <br />' in the above referenced sample, the laboratory analyzed a duplicate sample and reported one fish <br /> mortality in the 1,000 ml sample factor after 48 hours and a second fish mortality in the 1,000 ml <br /> sample factor after 96 hours The bioassay analysis Is summarized in Table 5, laboratory reports are <br />' in Appendix F <br /> • <br /> Advanced GeoEnvironmental,Inc <br /> 1 <br />