Laserfiche WebLink
Mr. Ken Price - 2 - • 14 June 2004 , <br /> As illustrated in the Annual 2003 Monitoring Report and First Semiannual 2004 Monitoring Report, <br /> constituent concentrations in groundwater downgradient of the soil excavation area declined by about an <br /> order of magnitude between 2002 and 2004. For example, in MW-27, downgradient of the excavation, <br /> 1,2-DCP decreased from about 150 ug/l in 2002 to 7 ug/1 in 2004, 1,2,3-TCP decreased from about 3 to <br /> 0.2 ug/l, atrazine decreased from about 4 to less than 0.5 ug/l, chlorobenzene decreased from about 4 to <br /> less than 0.5 ug/l, and nitrate decreased from about 200 mg/l to 50 mg/l in 2004. Regional Board staff <br /> believe that these dramatic declines in groundwater constituents are a direct result of MSRM's extensive <br /> soil removal and treatment activities. <br /> Lateral and Vertical Extent of Groundwater Constituents <br /> The intermediate water-bearing zone contains chlorobenzene at a concentration of about 1.3 ug/l in one <br /> monitoring well (MW-18), which underlies the fornler wash pad. Other constituents of concern <br /> identified in the intermediate zone prior to 2000 are no longer detected. <br /> In the shallow water-bearing zone, the data show that nitrate (as nitrogen) concentrations in the furthest <br /> downgradient monitoring wells (MW-23, MW-25, and MW-29)range from about 20 to 40 mg/1 and <br /> concentrations are stable, given the seasonal variation exhibited throughout the monitoring history. <br /> While chloride is present in these downgradient monitoring wells, the data show a potential for wide <br /> variation in background chloride concentrations, and it is not apparent whether the chloride detected is <br /> related to site activities. Organic constituents of concern are not detected in these downgradient <br /> monitoring wells. <br /> Constituents in the shallow monitoring wells between the facility and the furthest downgradient wells <br /> (MW-26, MW-27, MW-28) are declining in concentration, most notably since the soil excavation and <br /> treatment. Therefore, Regional Board staff concur that the plume is stable and defined. <br /> Prior to 2003, the center of mass of the groundwater pollution straddled the downgradient boundary of <br /> the facility with the adjacent residential subdivision. Since the soil removal and treatment activities in <br /> late 2001, concentrations of constituents of concern in groundwater have drastically decreased beneath <br /> the subdivision, and as a result, the center of mass of pollutants is currently beneath the facility. These <br /> reductions in groundwater pollutants were not yet apparent when Geomatrix prepared the FS/RO in mid- <br /> 2003. <br /> Feasibility Study/Remedial Options Evaluation Report <br /> In the FS/RO, MSRM evaluates four possible alternatives for remediation of groundwater, as listed <br /> below: <br /> • On-site phytoremediation with monitored natural attenuation for off-site constituents <br /> • Enhanced in situ bioremediation with monitored natural attenuation for chloride <br /> • In situ chemical oxidation with monitored natural attenuation for nitrate and chloride <br /> • Groundwater extraction, treatment with activated carbon and ion exchange, and discharge to sanitary <br /> sewer. <br /> Geomatrix Consultants identifies on-site phytoremediation as the preferred alternative. For the <br /> monitored natural attenuation component of this alternative, Geomatrix proposes to develop a <br />