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Mr. Ken Price - 3 - • <br /> 14 June 2004 <br /> contingency plan to "address potential future changes in site conditions that could result in loss of <br /> hydraulic control or plume migration beyond the existing monitoring system". <br /> We concur that on-site phytoremediation is a reasonable remedial strategy for groundwater at this site, <br /> provided that the recent trends of decreasing concentrations of constituents in off-site downgradient <br /> monitoring wells continue. If,however, increasing concentration trends in these off-site downgradient <br /> wells become apparent, then MSRM will be called upon to enact a contingency plan that implements an <br /> alternate or supplemental remediation strategy. <br /> The existing phytoremediation plot consists of about 1,500 eucalyptus trees that are about one year old. <br /> MSRM needs to provide a Cleanup Plan, including a contingency plan that identifies what criteria will <br /> determine an apparent increase in constituent concentrations in downgradient monitoring wells, what <br /> remedial action will be implemented if the contingency is triggered, and what additional preparation will <br /> be needed to fully execute this alternative. The Cleanup Plan also needs to include photographs of the <br /> existing trees. <br /> Analyses for 1,2,3-Trichloropropane <br /> In the Analyses for 1,2,3-Trichloropropane Report, Geomatrix presents a comparison of duplicate <br /> groundwater samples obtained from this site over two sampling events. The samples were analyzed for <br /> 1,2,3-trichloropropane by two different Department of Health Services (DHS) methods: Fumigant <br /> Method and Low Level Method. <br /> The Fumigant Method has a detection limit of 0.01 ug/l, and the Low Level Method has a detection limit <br /> of 0.005 ug/l. Thirty eight samples were analyzed in duplicate, with results ranging from 1.3 ug/l to less <br /> than 0.005 ug/l. The comparison of these sample sets shows that the Low Level Method typically results <br /> in a higher concentration of 1,2,3-TCP than the Fumigant Method. For detectable results, the <br /> concentration differences between the two analyses ranged from 8% to 82%. Twenty-two sample sets <br /> did not contain 1,2,3-TCP by either method. For two samples, the Fumigant Method returned an <br /> unqualified ND, and the Low Level Method returned a trace amount (below the quantitation limit). <br /> In conclusion, Geomatrix states that the additional cost of the Low Level Method ($250 per analysis <br /> versus $95 per analysis by the Fumigant Method) is not commensurate with the benefit of the lower <br /> detection limit possible with that method. <br /> We concur that for the majority of the monitoring, a detection limit of 0.01 ug/1 as is provided by the <br /> Fumigant Method is appropriate. The existing Monitoring and Reporting Program No. R5-2002-0831 <br /> (MRP) does not require the Low Level Method for 1,2,3-TCP. When MSRM requests that the MRP be <br /> ievised, or when otherwise asserting that the 1,2,3-TCP plume is reduced or stable, then the Low Level <br /> Method will be needed to support such statements. <br /> Summary <br /> The soil excavation and treatment that MSRM and Geomatrix conducted in late 2001 has reduced the <br /> extent of the groundwater plume such that on-site phytoremediation appears to be a reasonable <br /> remediation strategy to remove groundwater constituents. The phytoremediation plot that MSRM <br /> established for soil remediation in 2003 may serve the dual purposes of soil and groundwater <br /> remediation. <br />