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Rl KLEINFELDER <br /> File No. 20-3978-01.W 10 <br /> July 26, 1997 <br /> Arsenic was not detected in the stock (cattle pen) well, Production Wells 5 and 7, <br /> Monitoring Well 3 (downgradient of a portion of the wastewater ponds), Monitoring <br /> Well 4 (downgradient from the mud ponds), and Monitoring Well 5 (off-site <br /> upgradient well). Arsenic was detected above the MCL in Monitoring Well 1 and 2 <br /> (downgradient from the lime ponds). The concentrations present were similar to <br /> those revealed in past monitoring events at the site. Arsenic is a naturally occurring <br /> element and can exist in groundwater in very high concentrations such as that in the <br /> west side of the San Joaquin Valley. <br /> Barium concentrations exceed the MCL in monitoring wells MW-1 and MW-2 <br /> (downgradient from the lime ponds). Both concentrations, 1.4 mg/L and 1.1 mg/L <br /> respectively, only slightly exceed the MCL of 1.0 mg/L. The source of the barium is <br /> unknown. However, it should be noted that barium concentrations in the off-site <br /> upgradient monitoring well (MW-5) have exceeded the MCL for barium during past <br /> monitoring events associated with the ponds. The concentrations present were <br /> similar to those revealed in past monitoring events at the site. <br /> 3. The concentrations of bicarbonate alkalinity, boron, calcium, magnesium, potassium <br /> and sodium appear to indicate a "hard water" condition to be present in the samples <br /> obtained. This condition is evident in all of the samples. The highest concentrations <br /> present appear to be located adjacent to the lime ponds. However, hard water was <br /> also present in the upgradient, off-site well. No MCLS or SMCLs are listed for any <br /> of these analytes in 22CCR§64431 or 22CCR§64449, respectively. <br /> 4. Slightly elevated chloride concentrations existed on site. Water samples obtained <br /> from Monitoring Wells 2 and 4 exceeded the recommended SMCL as expressed in <br /> 22CCR§64449. In addition, the chloride results for the water sample taken from <br /> Monitoring Well 4 matched the "Upper" SMCL of 500 mg/L as expressed in <br /> 22CCR§64449. <br /> 5. Specific Conductance (EC) in the groundwater samples obtained exceeded the <br /> recommended SMCL (900 µmhos/cm) as expressed in 22CCR§64449 in all but the <br /> samples obtained from the stock(cattle pen)well. The exceedances also occurred for <br /> the off-site, upgradient well MW-5. Additionally, water samples obtained from <br /> Production Wells 5 and 7 matched the upper SMCL of 1600 µmhos/cm, while <br /> Monitoring Wells 1 through 5 exceeded it. In addition, Monitoring Wells 1, 2 and 4 <br /> exceeded the short term SMCL (2,200 µmhos/cm) Total Dissolved Solids (TDS) in <br /> groundwater were high in all but one of the samples obtained (stock (cattle pen) <br /> 20-3978-OI.WI012O17L155 Page 35 of 5O Copyright 1997,Kleinfelder,Inc. <br />