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Q � <br /> r U <br /> r <br /> t <br /> 3S1UW83d <br /> ' � 3WNOb1AN� <br /> Appendix C S N(1P <br /> Former CURTISS PONTIAC-CADILLAC soot 9 f <br /> 2450 Toste Road, Tracy, California /003b i <br /> OZONE INJECTION BENCH'SCALE STUDY ` AA IpA <br /> In preparation for ground water remediation utilizing ozone injection ythe CVRWQCB policy for <br /> the investigation,of UST_sites•requires the site determine limits of the detrimental, secondary <br /> consequences.geerated from in-situ ozone injection. <br /> Based upon results from several air-sparging and ozone-injection projects with similar geologic <br /> conditions, it has been AGE'S experience that iron fouling of sparge points has not been a concern <br /> to the site remediation. However, an Ozone Injection Bench Scale Study is proposed to determine <br /> whether general ozone injection into the subsurface has the potential to significantly increase the <br /> concentrations of metals which may secondarily degrade water quality.The main goal of the Bench <br /> Scale Study .is to assess productior n of hexavalent.chromium (Cr"),and to secondly measure <br /> concentration increases of the secondary metals and generatparameters,as well as the degradation <br /> of petroleum hydrocarbons. <br /> Baseline Analysis 4.1 <br /> For.assessment of baseline conditions done soil=boringtOZ--1,will-be-collected-with-sampling 1. <br /> MW-1 zintervals occurring--at-the 15 and73_5-f -interval <Gr er.-sam les-will=be=tak n f—o e <br /> onsite-mo itorin well, hV .1 an W a ;th 3:to:2 and to-T5 oft=interval;,respectively <br /> L� 5 S This will give a representa ive samp o e su surface soil ground water interface.Soil and ground <br /> C W.-• water samples will be analyzed by.a California Department of Public Health (CDPH)-certified 1 <br /> laboratory for the.following constituents: <br /> k <br /> • Total petroleum hydrocarbons quantified as gasoline (TPH-g) in accordance with EPA <br /> Method 8015 Modified; <br /> • `Benzene,toluene,ethyl-benzene and total xylenes(BTEX);the fuel additives methyl tertiary <br /> butyl ether(MTBE), tertiary butyl alcohol (TBA),di-isopropyl-ether(DIPE), ethyl tertiary ' <br /> butyl ether (ETBE), tertiary amyl methyl ether (TAME), ethylene dibromide (EDB) and <br /> 1,2-dichloroethane (1,2-DCA) in accordance with EPA Method 8260 Modified; • <br /> • I <br /> • Metals including antimony, arsenic, barium, beryllium; cadmium, calcium, chromium, <br /> cobalt,copper,iron,lead,mercury,magnesium,manganese,molybdenum,nickel,potassium, <br /> selenium, silver, sodium, thallium, vanadium, and zinc by EPA Method 200.8, and <br /> hexavalent chromium by EPA Method 218.6/DISTLC/3060A; <br /> • Standard mineral including chloride, fluoride, nitrate as N, and sulfate by EPA Method i <br /> 300.1; alkalinity by EPA Method 310.1; and total dissolved solids by EPA Method 160.1; <br /> i <br /> • General Minerals(metals;Al,Sb,As,Ba,Be,Ca,Cd,Cr,Co,Cu,Fe,Pb,Mg,Mn,Hg,Mo, <br /> K, Ni, Ag, Na, Se, Tl, W, V, and Zn) by EPA Method 200.8 and Hexachrome by EPA <br /> i <br />