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M We agitation as possible to reducd potential loss of volatile constituents. Major, ions, TDS, <br />- and metals analyses (in non -preserved containers) will be collected next followed by samples to <br />be collected in preserved containers. Containers will be filled directly from the disposable bailer, <br />immediately capped, and placed in a temperature -monitored iced chest. Caution will be used not <br />to overfill bottles containing a preservative. Temperature will be monitored by Placing a <br />thermometer in the chest and checkdng to make sure that there is'suffic;imt ice in the chest to <br />maintain a temperature of approximately 4 d Celsius. The laboratory . 3` . e� t'Y will measure; <br />docvinent, and report the temperature of the sample container upon arrival at the laboratory., <br />The analytical laboratory places a total of 2 ml of nitric acid in some of the I liter Crottles to <br />reduce the pH to below 2. 4n an annual basis an extra preserved bottle will be filled with <br />.groundwater and -the pH measured in the bottle.. It is'assumcd that the pH will be -below 2: If it <br />is not the field technician will add nitric acid in measured amounts until the pH is below 2- This <br />added quantity of acid will be placed in all the preserved bottics.during the following monitoring <br />rounds until it is checked again the following -year ; Sample.pH•-wtii- be- corzfizraed: at, the.: <br />laboratory and accorded. Deviations will be documented and reported by the laboratory - <br />Samples: to be submitted for metals analysis -will. be filtered in the field.. Filtering- will be <br />.performed using an in line filter mechanism which -uses the, pumping process -of .the- dedicated t <br />PAF to draw water through the'4 micron filter A new filter will be used at each well_ The new <br />fibers gill have a minimum of one filter volume of groundwater pressurized through them to- <br />reduca adsorption effects. The actual filtered-sample.will not be collected -until a minimum of <br />two filter volumes of groundwater hai been. passed through the filter. For welh witho ' <br />dedicated pumps, the samples ate transferred from the bailer, through a filter apparatus, into the <br />appropriate wimple container- The filter apparatus consists of a Pressure: Vessel, a hand --operated - <br />Pressure Pump, and a filter -cartridge- Water frim the bailer is placed in the pressure vessel and <br />c=ough air pressure (via the hand pump) is applied to force water through the filter cartridge into <br />the sample bottles_ The pressure vessel is washed in Alconox, steam cleaned, and rinsed with <br />deionized water between welts_ A new filter cartridge is used at each well. <br />Samples will be labeled with a unique sample identification number, project identification <br />number, sample location, and date and time sampled. Samples will be transported to the contrast <br />laboratory under strict chain -of -custody procedures- - <br />23-483849-FO1t231OR32S A-9 <br />July 14,2044 <br />Cop 74041000 Kkinfddere tile. �' <br />