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IV. Catc2ory C <br />1. CWC 134: Aqueous solution with total organic residues less than 10 percent <br />Site 12006 Quantity (lb)2010 quantity (lb) <br />LLNL 144 10 <br />1.1 National Ignition Facility Optics Onerations <br />The 2006 44 lbs of this waste stream (identified as CWC 134) waste stream was <br />generated from National Ignition Facility (NIF) optics operations. The same process <br />generated 41 lbs of the waste stream (identified as CWC 135) in 2010. This process is <br />already optimized for minimal waste generation. <br />CWC 135: Unspecified aqueous solution <br />Site 2006 Quantity (lb)2010 quantity (lb)' <br />LLNL 1342 14,863 <br />2.1 Optic etching <br />This waste stream is from NIF etching operations performed on new optics received from <br />the vendor. The process has been optimized to generate the minimal amount of waste <br />while producing the high quality optics required. For example, etchant is only changed <br />out after the solution is completely spent after 20 optics. About 40 gallons per year of <br />waste is generated from this process. In 2006, a total of 332 lbs of CWC 135 (241 lbs) <br />and CWC 791 (91 lbs) waste was generated by this process. In 2010, a total of 325 lbs of <br />CWC 131 (109 lbs) and CWC 135 (216 lbs) waste was generated. <br />An additional 101 lbs of Category C waste was included in the 2007 SB14 Plan total for <br />CWC 135. This was from research and development activities associated with optics <br />proof -of -concept research. In 2010, 37 lbs of waste was generated from this process, <br />which varies from year to year. This waste stream is not included in the 2011 SB14 Plan <br />because it fits within the exempted category: "Wastes generated from laboratory scale <br />research". It is mentioned here because it was previously included in the 2007 S1314 <br />Plan. <br />Note that in 2010, 109 lbs of the optics processing waste stream was characterized as <br />CWC 131. The remaining 216 lbs of waste was characterized as CWC 135. They are <br />combined here since they are from the same optics processing operation. <br />Other etching operations generate CWC 135 wastestream periodically based on the <br />volume of new optics required for programmatic operations. The process has been <br />optimized to generate the minimal amount of waste while producing the high quality <br />optics required. For example, optics are batched to minimize solution change out <br />between optic types, and baths are reused. During late 2009 and early 2010 a large <br />number of new optics were processed resulting in 4,606 lbs of waste generated in 2010. <br />Another batch is currently scheduled through early 2012. Beyond 2012, this process is <br />expected to be operated at approximately 50% capacity to support ongoing NIF <br />operations. <br />In 2009, NIF started implementation of an optics repair process to extend the life of the <br />optics. This operation continued to expand in 2010 and reduces both the need to acquire <br />new replacement optics and the chemicals used to process them. <br />An additional 41 lbs of CWC 135 waste was generated as part of other NIF optics <br />operations as discussed in Section 1.1 (Category C CWC 134). <br />September 1, 2011 SS 14 Report 35 September 1, 2011 SB 14 Report 36 <br />