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Ground Zero Analysis, Inc. <br />HEALTH AND SAFETY PLAN <br />JOB HAZARD ANALYSIS AND SUMMARY <br />Chemical Hazards <br />TASK(S) CHEMICAL PEL/STEL/IDLH <br />(SOIL, WATER, <br />AIR, ETC.) <br />KNOWN <br />CONCENTRATION <br />SIGNS/SYMPTOMS <br />I TPH gasoline None Established <br />22,000 ppm (soil) <br />1,900 ppm (water) <br />Headache; nasal, eye, skin and <br />respiratory irritation, drowsiness, fatigue, pneumonitis, nausea, <br />asphyxia, CNS depression. <br />I Benzene <br />PEL 0.1 ppm (NIOSH)/ <br />1 ppm (OSHA) <br />STEL 1 ppm (NIOSH)/ <br />5 ppm (OSHA) <br />IDLH 3,000 ppm <br />0.68 ppm (soil) <br />33 ppm (water) <br />Irritation of eyes, nose, respiratory <br />sys; giddiness, headaches, nausea, <br />staggered gait, fatigue, anorexia, <br />lassitude, dermatitis, human <br />carcinogen. <br />I Toluene <br />PEL 100 ppm <br />STEL 150 ppm <br />IDLH 2,000 ppm <br />1, 900 ppm (soil) <br />Non-detect (water) <br />Fatigue, weakness; confusion, <br />euphoria, dizziness, headache; dilated <br />pupils, tearing, nervousness, muscular <br />fatigue, insomnia, paresthesia, <br />dermatitis. <br />I Ethylbenzene <br />PEL 100 ppm <br />STEL 125 ppm <br />IDLH 2,000 ppm <br />640 ppm (soil) <br />4.5 ppm (water) <br />Initation of eyes, mucous membranes; <br />headache, dermatitis, narcosis, coma. <br />I Xylenes <br />PEL 100 ppm <br />STEL 150 ppm <br />IDLH 10,000 ppm <br />3,100 ppm (soil) <br />10 ppm (water) <br />Dizziness, excitement, drowsiness, <br />incoordination, staggering gait, <br />irritation of eyes, nose, throat; comeal <br />vacuolization; anorexia, nausea, <br />vomiting, abdominal pain; dermatitis. <br />I NITBE PEL 50 ppm (ACG1H) 0.00062 ppm (soil) <br />3.4 ppm (water) <br />Irritation, nausea, vomiting, and <br />diarrhea, and central nervous system <br />(brain) effects similar to alcohol <br />intoxication; liritation to the nose, <br />throat, lungs and respiratory tract. <br />PAGE 3